Incredibly light, strong materials recover original shape after being smashed

Incredibly light, strong materials recover original shape after being smashed

  4:10:00 PM    Science Lover

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Materials scientists have developed a method for creating new structural materials by taking advantage of the unusual properties that solids can have at the nanometer scale. They have used the method to produce a ceramic (e.g., a piece of chalk or a brick) that contains about 99.9 percent air yet is incredibly strong and can recover its original shape after being smashed by more than 50 percent.

This sequence shows how the Greer Lab's three-dimensional,
ceramic nanolattices can recover after being compressed by
more than 50 percent. Clockwise, from left to right, an alumina
nanolattice before compression, during compression, fully
compressed, and recovered following compression.

Credit: Lucas Meza/Caltech

Imagine a balloon that could float without using any lighter-than-air gas. Instead, it could simply have all of its air sucked out while maintaining its filled shape. Such a vacuum balloon, which could help ease the world's current shortage of helium, can only be made if a new material existed that was strong enough to sustain the pressure generated by forcing out all that air while still being lightweight and flexible. 

Caltech materials scientist Julia Greer and her colleagues are on the path to developing such a material and many others that possess unheard-of combinations of properties. For example, they might create a material that is thermally insulating but also extremely lightweight, or one that is simultaneously strong, lightweight, and nonbreakable -- properties that are generally thought to be mutually exclusive.

Greer's team has developed a method for constructing new structural materials by taking advantage of the unusual properties that solids can have at the nanometer scale, where features are measured in billionths of meters. In a paper published in the September 12 issue of the journal Science, the Caltech researchers explain how they used the method to produce a ceramic (e.g., a piece of chalk or a brick) that contains about 99.9 percent air yet is incredibly strong, and that can recover its original shape after being smashed by more than 50 percent.

"Ceramics have always been thought to be heavy and brittle," says Greer, a professor of materials science and mechanics in the Division of Engineering and Applied Science at Caltech. "We're showing that in fact, they don't have to be either. This very clearly demonstrates that if you use the concept of the nanoscale to create structures and then use those nanostructures like LEGO to construct larger materials, you can obtain nearly any set of properties you want. You can create materials by design."

The researchers use a direct laser writing method called two-photon lithography to "write" a three-dimensional pattern in a polymer by allowing a laser beam to crosslink and harden the polymer wherever it is focused. The parts of the polymer that were exposed to the laser remain intact while the rest is dissolved away, revealing a three-dimensional scaffold. That structure can then be coated with a thin layer of just about any kind of material -- a metal, an alloy, a glass, a semiconductor, etc. Then the researchers use another method to etch out the polymer from within the structure, leaving a hollow architecture.

The applications of this technique are practically limitless, Greer says. Since pretty much any material can be deposited on the scaffolds, the method could be particularly useful for applications in optics, energy efficiency, and biomedicine. For example, it could be used to reproduce complex structures such as bone, producing a scaffold out of biocompatible materials on which cells could proliferate.

In the latest work, Greer and her students used the technique to produce what they call three-dimensional nanolattices that are formed by a repeating nanoscale pattern. After the patterning step, they coated the polymer scaffold with a ceramic called alumina (i.e., aluminum oxide), producing hollow-tube alumina structures with walls ranging in thickness from 5 to 60 nanometers and tubes from 450 to 1,380 nanometers in diameter.

Greer's team next wanted to test the mechanical properties of the various nanolattices they created. Using two different devices for poking and prodding materials on the nanoscale, they squished, stretched, and otherwise tried to deform the samples to see how they held up.

They found that the alumina structures with a wall thickness of 50 nanometers and a tube diameter of about 1 micron shattered when compressed. That was not surprising given that ceramics, especially those that are porous, are brittle. However, compressing lattices with a lower ratio of wall thickness to tube diameter -- where the wall thickness was only 10 nanometers -- produced a very different result.

"You deform it, and all of a sudden, it springs back," Greer says. "In some cases, we were able to deform these samples by as much as 85 percent, and they could still recover."

To understand why, consider that most brittle materials such as ceramics, silicon, and glass shatter because they are filled with flaws -- imperfections such as small voids and inclusions. The more perfect the material, the less likely you are to find a weak spot where it will fail. Therefore, the researchers hypothesize, when you reduce these structures down to the point where individual walls are only 10 nanometers thick, both the number of flaws and the size of any flaws are kept to a minimum, making the whole structure much less likely to fail.

"One of the benefits of using nanolattices is that you significantly improve the quality of the material because you're using such small dimensions," Greer says. "It's basically as close to an ideal material as you can get, and you get the added benefit of needing only a very small amount of material in making them."

The Greer lab is now aggressively pursuing various ways of scaling up the production of these so-called meta-materials.

Story Source: http://www.sciencedaily.com/releases/2014/09/140911135450.htm

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Small in Size, Big On Power: New Microbatteries the Most Powerful Yet

Small in Size, Big On Power: New Microbatteries the Most Powerful Yet

  9:32:00 AM    Science Lover

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Though they be but little, they are fierce. The most powerful batteries on the planet are only a few millimeters in size, yet they pack such a punch that a driver could use a cellphone powered by these batteries to jump-start a dead car battery -- and then recharge the phone in the blink of an eye. 

The graphic illustrates a high power battery technology from the University of Illinois. Ions flow between three-dimensional micro-electrodes in a lithium ion battery. (Credit: Image courtesy of the Beckman Institute for Advanced Science and Technology)

Developed by researchers at the University of Illinois at Urbana-Champaign, the new microbatteries out-power even the best supercapacitors and could drive new applications in radio communications and compact electronics.

Led by William P. King, the Bliss Professor of mechanical science and engineering, the researchers published their results in the April 16 issue of Nature Communications.

"This is a whole new way to think about batteries," King said. "A battery can deliver far more power than anybody ever thought. In recent decades, electronics have gotten small. The thinking parts of computers have gotten small. And the battery has lagged far behind. This is a microtechnology that could change all of that. Now the power source is as high-performance as the rest of it."

With currently available power sources, users have had to choose between power and energy. For applications that need a lot of power, like broadcasting a radio signal over a long distance, capacitors can release energy very quickly but can only store a small amount. For applications that need a lot of energy, like playing a radio for a long time, fuel cells and batteries can hold a lot of energy but release it or recharge slowly.

"There's a sacrifice," said James Pikul, a graduate student and first author of the paper. "If you want high energy you can't get high power; if you want high power it's very difficult to get high energy. But for very interesting applications, especially modern applications, you really need both. That's what our batteries are starting to do. We're really pushing into an area in the energy storage design space that is not currently available with technologies today."

The new microbatteries offer both power and energy, and by tweaking the structure a bit, the researchers can tune them over a wide range on the power-versus-energy scale.

The batteries owe their high performance to their internal three-dimensional microstructure. Batteries have two key components: the anode (minus side) and cathode (plus side). Building on a novel fast-charging cathode design by materials science and engineering professor Paul Braun's group, King and Pikul developed a matching anode and then developed a new way to integrate the two components at the microscale to make a complete battery with superior performance.

With so much power, the batteries could enable sensors or radio signals that broadcast 30 times farther, or devices 30 times smaller. The batteries are rechargeable and can charge 1,000 times faster than competing technologies -- imagine juicing up a credit-card-thin phone in less than a second. In addition to consumer electronics, medical devices, lasers, sensors and other applications could see leaps forward in technology with such power sources available.

"Any kind of electronic device is limited by the size of the battery -- until now," King said. "Consider personal medical devices and implants, where the battery is an enormous brick, and it's connected to itty-bitty electronics and tiny wires. Now the battery is also tiny."

Now, the researchers are working on integrating their batteries with other electronics components, as well as manufacturability at low cost.

"Now we can think outside of the box," Pikul said. "It's a new enabling technology. It's not a progressive improvement over previous technologies; it breaks the normal paradigms of energy sources. It's allowing us to do different, new things."

The National Science Foundation and the Air Force Office of Scientific Research supported this work. King also is affiliated with the Beckman Institute for Advanced Science and Technology; the Frederick Seitz Materials Research Laboratory; the Micro and Nanotechnology Laboratory; and the department of electrical and computer engineering at the U. of I.

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'Invisibility': Key to Better Electronics?

'Invisibility': Key to Better Electronics?

  11:07:00 AM    Science Lover

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Visual 'Cloaking' Technology Enables More Efficient Transfer of Electrons

 A new approach that allows objects to become "invisible" has now been applied to an entirely different area: letting particles "hide" from passing electrons, which could lead to more efficient thermoelectric devices and new kinds of electronics.

Diagram shows the 'probability flux' of electrons, a 
representation of the paths of electrons as they pass through 
an 'invisible' nanoparticle. While the paths are bent as 
they enter the particle, they are subsequently bent back 
so that they re-emerge from the other side on the same 
trajectory they started with — just as if the particle 
wasn't there. (Credit: Image courtesy Bolin Liao et al.)

The concept -- developed by MIT graduate student Bolin Liao, former postdoc Mona Zebarjadi (now an assistant professor at Rutgers University), research scientist Keivan Esfarjani, and mechanical engineering professor Gang Chen -- is described in a paper in the journal Physical Review Letters.

Normally, electrons travel through a material in a way that is similar to the motion of electromagnetic waves, including light; their behavior can be described by wave equations. That led the MIT researchers to the idea of harnessing the cloaking mechanisms developed to shield objects from view -- but applying it to the movement of electrons, which is key to electronic and thermoelectric devices.

Previous work on cloaking objects from view has relied on so-called metamaterials made of artificial materials with unusual properties. The composite structures used for cloaking cause light beams to bend around an object and then meet on the other side, resuming their original path -- making the object appear invisible.

"We were inspired by this idea," says Chen, the Carl Richard Soderberg Professor of Power Engineering at MIT, who decided to study how it might apply to electrons instead of light. But in the new electron-cloaking material developed by Chen and his colleagues, the process is slightly different.

The MIT researchers modeled nanoparticles with a core of one material and a shell of another. But in this case, rather than bending around the object, the electrons do actually pass through the particles: Their paths are bent first one way, then back again, so they return to the same trajectory they began with.

In computer simulations, the concept appears to work, Liao says. Now, the team will try to build actual devices to see whether they perform as expected. "This was a first step, a theoretical proposal," Liao says. "We want to carry on further research on how to make some real devices out of this strategy."

While the initial concept was developed using particles embedded in a normal semiconductor substrate, the MIT researchers would like to see if the results can be replicated with other materials, such as two-dimensional sheets of graphene, which might offer interesting additional properties.

The MIT researchers' initial impetus was to optimize the materials used in thermoelectric devices, which produce an electrical current from a temperature gradient. Such devices require a combination of characteristics that are hard to obtain: high electrical conductivity (so the generated current can flow freely), but low thermal conductivity (to maintain a temperature gradient). But the two types of conductivity tend to coexist, so few materials offer these contradictory characteristics. The team's simulations show this electron-cloaking material could meet these requirements unusually well.

The simulations used particles a few nanometers in size, matching the wavelength of flowing electrons and improving the flow of electrons at particular energy levels by orders of magnitude compared to traditional doping strategies. This might lead to more efficient filters or sensors, the researchers say. As the components on computer chips get smaller, Chen says, "we have to come up with strategies to control electron transport," and this might be one useful approach.

The concept could also lead to a new kind of switches for electronic devices, Chen says. The switch could operate by toggling between transparent and opaque to electrons, thus turning a flow of them on and off. "We're really just at the beginning," he says. "We're not sure how far this is going to go yet, but there is some potential" for significant applications.

Xiang Zhang, a professor of mechanical engineering at the University of California at Berkeley who was not involved in this research, says "this is very exciting work" that expands the concept of cloaking to the domain of electrons. The authors, he says, "uncovered a very interesting approach that may be very useful to thermoelectric applications."

This research was funded by the U.S. Department of Energy (DOE) through MIT's Solid-State Solar-Thermal Energy Conversion center, a DOE Energy Frontier Research Center.

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Electricity from the nose: Engineers make power from human respiration

Electricity from the nose: Engineers make power from human respiration

  8:59:00 AM    Science Lover

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The same piezoelectric effect that ignites your gas grill with the push of a button could one day power sensors in your body via the respiration in your nose.

Graduate Student Jian Shi and Materials Science and
Engineering Assistant Professor Xudong Wang
demonstrate a material that could be used to
capture energy from respiration.

Writing in the September issue of the journal Energy and Environmental Science, Materials Science and Engineering Assistant Professor Xudong Wang, postdoctoral Researcher Chengliang Sun and graduate student Jian Shi report creating a plastic microbelt that vibrates when passed by low-speed airflow such as human respiration.

In certain materials, such as the polyvinylidene fluoride (PVDF) used by Wang’s team, an electric charge accumulates in response to applied mechanical stress. This is known as the piezoelectric effect. The researchers engineered PVDF to generate sufficient electrical energy from respiration to operate small electronic devices.



“Basically, we are harvesting mechanical energy from biological systems. The airflow of normal human respiration is typically below about two meters per second,” says Wang. “We calculated that if we could make this material thin enough, small vibrations could produce a microwatt of electrical energy that could be useful for sensors or other devices implanted in the face.”

Researchers are taking advantage of advances in nanotechnology and miniaturized electronics to develop a host of biomedical devices that could monitor blood glucose for diabetics or keep a pacemaker battery charged so that it would not need replacing. What’s needed to run these tiny devices is a miniscule power supply. Waste energy in the form or blood flow, motion, heat, or in this case respiration, offers a consistent source of power.

Wang’s team used an ion-etching process to carefully thin material while preserving its piezoelectric properties. With improvements, he believes the thickness can be controlled down to the submicron level. Because PVDF is biocompatible, he says the development represents a significant advance toward creating a practical micro-scale device for harvesting energy from respiration.

Provided by University of Wisconsin-Madison

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Soft Memory Device Opens Door to New Biocompatible Electronics

Soft Memory Device Opens Door to New Biocompatible Electronics

  12:47:00 AM    Science Lover

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Researchers from North Carolina State University have developed a memory device that is soft and functions well in wet environments -- opening the door to a new generation of biocompatible electronic devices.

Researchers have created a memory device with the 
physical properties of Jell-O, and that functions well 
in wet environments. (Credit: Michael Dickey, North 
Carolina State University)

"We've created a memory device with the physical properties of Jell-O," says Dr. Michael Dickey, an assistant professor of chemical and biomolecular engineering at NC State and co-author of a paper describing the research.

Conventional electronics are typically made of rigid, brittle materials and don't function well in a wet environment. "Our memory device is soft and pliable, and functions extremely well in wet environments -- similar to the human brain," Dickey says.

Prototypes of the device have not yet been optimized to hold significant amounts of memory, but work well in environments that would be hostile to traditional electronics. The devices are made using a liquid alloy of gallium and indium metals set into water-based gels, similar to gels used in biological research.

The device's ability to function in wet environments, and the biocompatibility of the gels, mean that this technology holds promise for interfacing electronics with biological systems -- such as cells, enzymes or tissue. "These properties may be used for biological sensors or for medical monitoring," Dickey says.



The device functions much like so-called "memristors," which are vaunted as a possible next-generation memory technology. The individual components of the "mushy" memory device have two states: one that conducts electricity and one that does not. These two states can be used to represent the 1s and 0s used in binary language. Most conventional electronics use electrons to create these 1s and 0s in computer chips. The mushy memory device uses charged molecules called ions to do the same thing.

In each of the memory device's circuits, the metal alloy is the circuit's electrode and sits on either side of a conductive piece of gel. When the alloy electrode is exposed to a positive charge it creates an oxidized skin that makes it resistive to electricity. We'll call that the 0. When the electrode is exposed to a negative charge, the oxidized skin disappears, and it becomes conducive to electricity. We'll call that the 1.

Normally, whenever a negative charge is applied to one side of the electrode, the positive charge would move to the other side and create another oxidized skin -- meaning the electrode would always be resistive. To solve that problem, the researchers "doped" one side of the gel slab with a polymer that prevents the formation of a stable oxidized skin. That way one electrode is always conducive -- giving the device the 1s and 0s it needs for electronic memory.

The paper was published online July 4 by Advanced Materials. The paper was co-authored by NC State Ph.D. students Hyung-Jun Koo and Ju-Hee So, and NC State INVISTA Professor of Chemical and Biomolecular Engineering Orlin Velev. The research was supported by the National Science Foundation and the U.S. Department of Energy.

NC State's Department of Chemical and Biomolecular Engineering is part of the university's College of Engineering.

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Security holes discovered in iPhones, iPads

Security holes discovered in iPhones, iPads

  9:22:00 PM    Science Lover

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New security holes in iPhones, iPads stir fears about attacks; 'jailbreaking' in spotlight

A new security hole has opened up in Apple Inc.'s iPhone, iPad and iPod Touch devices, raising alarms about the susceptibility of some of the world's hottest tech gadgets to hacker attacks.

Flaws in the software running those devices came to light after a German security agency warned that criminals could use them to steal confidential data off the devices. Apple, the world's largest technology company by market value, said Thursday that it is working on a fix that will be distributed in an upcoming software upgrade.

With the security hole, an attacker can get malicious software onto a device by tricking its owner into clicking an infected PDF file. Germany's Federal Office for Information Security called the flaws "critical weaknesses" in Apple's iOS operating system.

Internet-connected mobile devices are still subject to fewer attacks than personal computer, but they could eventually prove a juicy target for hackers because they are warehouses of confidential banking, e-mail, calendar, contact and other data.

Software vulnerabilities are discovered all the time. What makes the latest discovery alarming is that the weaknesses are already being actively exploited - albeit in a consensual way.



The latest concerns were prompted by the emergence of a new version of a program to allow Apple devices to run any software and circumvent the restrictions that Apple notoriously retains over software distributed through its online store. There are security risks of doing so, but many people find it liberating to install their own software.

Although this program is something people would seek out, the weaknesses that its authors discovered could easily be used for malice, security experts say.

There is an irony in the controversy: The site distributing the program offers a fix for the problem, but to get the fix, a user has to first install the program in question. So a user must defy Apple's restrictions to get the protection until Apple comes up with a fix of its own.

Charlie Miller, a prominent hacker of Apple products, said it likely took months to develop the program to break Apple's restrictions, but a criminal might need only a day or two to modify it for nefarious purposes.

Apple Inc. spokeswoman Bethan Lloyd said Thursday the company is "aware of this reported issue and developing a fix." She would not say when the update will be available.

One reason for gadget owners to take heart: Attacks on smartphones and other Internet gadgets are still relatively rare. One reason is PC-based attacks are still highly lucrative. Still, vulnerabilities such as the ones Apple is confronting show that consumers should take care of securing their mobile devices as they would their home computer.

"These things are computers - they're just small, portable computers that happen to have a phone tacked onto them," said Marc Fossi, manager of research and development for Symantec Security Response. "You've got to treat them more like a computer than a phone. You have to be aware of what's going on with these devices."

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Energy Harvesting: Nanogenerators Grow Strong Enough to Power Small Conventional Electronic Devices

Energy Harvesting: Nanogenerators Grow Strong Enough to Power Small Conventional Electronic Devices

  10:22:00 AM    Science Lover

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Blinking numbers on a liquid-crystal display (LCD) often indicate that a device's clock needs resetting. But in the laboratory of Zhong Lin Wang at Georgia Tech, the blinking number on a small LCD signals the success of a five-year effort to power conventional electronic devices with nanoscale generators that harvest mechanical energy from the environment using an array of tiny nanowires.

In a new technique for producing nanogenerators,
researchers transfer vertically-aligned nanowires to a 
flexible substrate. (Credit: Courtesy of Zhong Lin Wang)

In this case, the mechanical energy comes from compressing a nanogenerator between two fingers, but it could also come from a heartbeat, the pounding of a hiker's shoe on a trail, the rustling of a shirt, or the vibration of a heavy machine. While these nanogenerators will never produce large amounts of electricity for conventional purposes, they could be used to power nanoscale and microscale devices -- and even to recharge pacemakers or iPods.

Wang's nanogenerators rely on the piezoelectric effect seen in crystalline materials such as zinc oxide, in which an electric charge potential is created when structures made from the material are flexed or compressed. By capturing and combining the charges from millions of these nanoscale zinc oxide wires, Wang and his research team can produce as much as three volts -- and up to 300 nanoamps.

"By simplifying our design, making it more robust and integrating the contributions from many more nanowires, we have successfully boosted the output of our nanogenerator enough to drive devices such as commercial liquid-crystal displays, light-emitting diodes and laser diodes," said Wang, a Regents' professor in Georgia Tech's School of Materials Science and Engineering. "If we can sustain this rate of improvement, we will reach some true applications in healthcare devices, personal electronics, or environmental monitoring."

Recent improvements in the nanogenerators, including a simpler fabrication technique, were reported online last week in the journal Nano Letters. Earlier papers in the same journal and in Nature Communications reported other advances for the work, which has been supported by the Defense Advanced Research Projects Agency (DARPA), the U.S. Department of Energy, the U.S. Air Force, and the National Science Foundation.

"We are interested in very small devices that can be used in applications such as health care, environmental monitoring and personal electronics," said Wang. "How to power these devices is a critical issue."

The earliest zinc oxide nanogenerators used arrays of nanowires grown on a rigid substrate and topped with a metal electrode. Later versions embedded both ends of the nanowires in polymer and produced power by simple flexing. Regardless of the configuration, the devices required careful growth of the nanowire arrays and painstaking assembly.

In the latest paper, Wang and his group members Youfan Hu, Yan Zhang, Chen Xu, Guang Zhu and Zetang Li reported on much simpler fabrication techniques. First, they grew arrays of a new type of nanowire that has a conical shape. These wires were cut from their growth substrate and placed into an alcohol solution.

The solution containing the nanowires was then dripped onto a thin metal electrode and a sheet of flexible polymer film. After the alcohol was allowed to dry, another layer was created. Multiple nanowire/polymer layers were built up into a kind of composite, using a process that Wang believes could be scaled up to industrial production.

When flexed, these nanowire sandwiches -- which are about two centimeters by 1.5 centimeters -- generated enough power to drive a commercial display borrowed from a pocket calculator.

Wang says the nanogenerators are now close to producing enough current for a self-powered system that might monitor the environment for a toxic gas, for instance, then broadcast a warning. The system would include capacitors able to store up the small charges until enough power was available to send out a burst of data.

While even the current nanogenerator output remains below the level required for such devices as iPods or cardiac pacemakers, Wang believes those levels will be reached within three to five years. The current nanogenerator, he notes, is nearly 100 times more powerful than what his group had developed just a year ago.

Writing in a separate paper published in October in the journal Nature Communications, group members Sheng Xu, Benjamin J. Hansen and Wang reported on a new technique for fabricating piezoelectric nanowires from lead zirconate titanate -- also known as PZT. The material is already used industrially, but is difficult to grow because it requires temperatures of 650 degrees Celsius.

In the paper, Wang's team reported the first chemical epitaxial growth of vertically-aligned single-crystal nanowire arrays of PZT on a variety of conductive and non-conductive substrates. They used a process known as hydrothermal decomposition, which took place at just 230 degrees Celsius.

With a rectifying circuit to convert alternating current to direct current, the researchers used the PZT nanogenerators to power a commercial laser diode, demonstrating an alternative materials system for Wang's nanogenerator family. "This allows us the flexibility of choosing the best material and process for the given need, although the performance of PZT is not as good as zinc oxide for power generation," he explained.

And in another paper published in Nano Letters, Wang and group members Guang Zhu, Rusen Yang and Sihong Wang reported on yet another advance boosting nanogenerator output. Their approach, called "scalable sweeping printing," includes a two-step process of (1) transferring vertically-aligned zinc oxide nanowires to a polymer receiving substrate to form horizontal arrays and (2) applying parallel strip electrodes to connect all of the nanowires together.

Using a single layer of this structure, the researchers produced an open-circuit voltage of 2.03 volts and a peak output power density of approximately 11 milliwatts per cubic centimeter.

"From when we got started in 2005 until today, we have dramatically improved the output of our nanogenerators," Wang noted. "We are within the range of what's needed. If we can drive these small components, I believe we will be able to power small systems in the near future. In the next five years, I hope to see this move into application."

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Semiconductor Could Turn Heat Into Computing Power

Semiconductor Could Turn Heat Into Computing Power

  9:59:00 AM    Science Lover

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Computers might one day recycle part of their own waste heat, using a material being studied by researchers at Ohio State University.

The material is a semiconductor called gallium manganese arsenide. In the early online edition of Nature Materials, researchers describe the detection of an effect that converts heat into a quantum mechanical phenomenon – known as spin – in a semiconductor.

Once developed, the effect could enable integrated circuits that run on heat, rather than electricity.

Roberto Myers

This research merges two cutting-edge technologies: thermo-electricity and spintronics, explained team leaders Joseph Heremans, Ohio Eminent Scholar in Nanotechnology, and Roberto Myers, assistant professor of materials science and electrical engineering at Ohio State University.

Joseph Heremans

Researchers around the world are working to develop electronics that utilize the spin of electrons to read and write data. So-called “spintronics” are desirable because in principle they could store more data in less space, process data faster, and consume less power.

Myers and Heremans are trying to combine spintronics with thermo-electronics – that is, devices that convert heat to electricity.

The hybrid technology, “thermo-spintronics,” would convert heat to electron spin.

In so doing, thermo-spintronics could solve two problems for the computing industry: how to remove waste heat, and how to boost computing power without creating more heat.

“Spintronics is considered as a possible basis for new computers in part because the technology is claimed to produce no heat. Our measurements shed light on the thermodynamics of spintronics, and may help address the validity of this claim,” Heremans said.

In fact, as the electronics industry tries to build smaller, denser computer circuits, a main limiting factor is the heat those circuits produce, said Myers.

“All of the computers we have now could actually run much faster than they do, but they’re not allowed to – because if they did, they would fail after a short time,” Myers said. “So a huge amount of money in the semiconductor industry is put toward thermal management.”

In one possible use of thermo-spintronics, a device could sit atop a traditional microprocessor, and siphon waste heat away to run additional memory or computation. Myers noted that such applications are still a long way off.

The researchers studied how heat can be converted to spin polarization– an effect called the spin-Seebeck effect. It was first identified by researchers at Tohoku University and reported in a 2008 paper in the journal Nature. Those researchers detected the effect in a piece of metal, rather than a semiconductor.

The new measurements, carried out by team member Christopher Jaworski, doctoral student of mechanical engineering at Ohio State, provide the first independent verification of the effect in a semiconductor material called gallium manganese arsenide.

While gallium arsenide is a semiconductor used in cell phones today, the addition of the element manganese endows the material with magnetic properties.

Samples of this material were carefully prepared into thin single-crystal films by collaborators Shawn Mack and Professor David Awschalom at the University of California at Santa Barbara, who also assisted with interpretation of the results. Jing Yang, doctoral student of materials science and engineering at Ohio State, then processed the samples for the experiment.

In this type of material, the spins of the charges line up parallel with the orientation of the sample’s overall magnetic field. So when the Ohio State researchers were trying to detect the spins of the electrons, they were really measuring whether the electrons in any particular area of the material were oriented as “spin-up” or “spin-down.”

In the experiment, they heated one side of the sample, and then measured the orientations of spins on the hot side and the cool side. On the hot side, the electrons were oriented in the spin-up direction, and on the cool side, they were spin-down.

The researchers also discovered, to their own surprise, that two pieces of the material do not need to be physically connected for the effect to propagate from one to the other.

They scraped away a portion of the sample with a file, to create two pieces of material separated by a tiny gap. If the spin effect were caused by electrical conduction – that is, electrons flowing from one part of the material to the other – then the gap would block the effect from spreading. Again, they applied heat to one side.

The effect persisted.

“We figured that each piece would have its own distribution of spin-up and spin-down electrons,” said Myers. “Instead, one side of the first piece was spin up, and the far side of the second piece was spin down. The effect somehow crossed the gap.”

“The original spin-Seebeck detection by the Tohoku group baffled all theoreticians,” Heremans added. “In this study, we’ve independently confirmed those measurements on a completely different material. We’ve proven we can get the same results as the Tohoku group, even when we take the measurements on a sample that’s been separated into two pieces, so that electrons couldn’t possibly pass between them.”

Despite these new experiments, the origin of the spin-Seebeck effect remains a mystery.

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Nano Antenna Concentrates Light

Nano Antenna Concentrates Light

  8:15:00 PM    Science Lover

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Everybody who's ever used a TV, radio or cell phone knows what an antenna does: It captures the aerial signals that make those devices practical. A lab at Rice University has built an antenna that captures light in the same way, at a small scale that has big potential.

This is a colorized scanning electron microscope 
image of gold tips in a nanogap device used in 
experiments to capture and amplify light. 
(Credit: Natelson Lab/Rice University)

Condensed matter physicist Doug Natelson and graduate student Dan Ward have found a way to make an optical antenna from two gold tips separated by a nanoscale gap that gathers light from a laser. The tips "grab the light and concentrate it down into a tiny space," Natelson said, leading to a thousand-fold increase in light intensity in the gap.

Getting an accurate measurement of the effect is a first, said Natelson, who reported the results in the September 19 online edition of the journal Nature Nanotechnology. He expects the discovery will be useful in the development of tools for optics and for chemical and biological sensing, even at the single-molecule scale, with implications for industrial safety, defense and homeland security.

The paper by Natelson, Ward and their colleagues in Germany and Spain details the team's technique, which involves shining laser light into the gap between a pair of gold tips less than a nanometer apart -- about a hundred-thousandth the width of a human hair.

"You can ignore the fact that your car antenna is built out of atoms; it just works," said Natelson, a Rice professor of physics and astronomy, and also electrical and computer engineering. "But when you have tiny pieces of metal very close to each other, you have to worry about all the details. The fields are going to be big, the situation's going to be complicated and you're really constrained. We've been able to use some physics that only come into play when things are very close together to help figure out what's going on."

The key to measuring light amplification turned out to be measuring something else, specifically the electrical current flowing between the gold tips.

Putting the nanotips so close together allows charge to flow via quantum tunneling as the electrons are pushed from one side to the other. The researchers could get electrons moving by pushing them at low frequencies with a voltage, in a highly controllable, measurable way. They could also get them flowing by shining the laser, which pushes the charge at the very high frequency of the light. Being able to compare the two processes set a standard by which the light amplification could be determined, Natelson said. Their German and Spanish coauthors helped supply the necessary theoretical justification for the analysis.

The amplification is a plasmonic effect, Natelson said. Plasmons, which may be excited by light, are oscillating electrons in metallic structures that act like ripples in a pool. "You've got a metal structure, you shine light on it, the light makes the electrons in this metal structure slosh around," he said. "You can think of the electrons in the metal as an incompressible fluid, like water in a bathtub. And when you get them sloshing back and forth, you get electric fields.

"At the surfaces of the metal, these fields can be very big -- much bigger than those from the original radiation," he said. "What was hard to measure was just how big. We didn't know how much the two sides were sloshing up and down -- and that's exactly the thing we care about."

By simultaneously measuring the low-frequency electrically driven and the high-frequency optically driven currents between the tips, "we can figure out the voltage zinging back and forth at the really high frequencies that are characteristic of light," he said.

Natelson said his lab's homebuilt apparatus, which combines nanoscale electronics and optics, is fairly unusual. "There are a lot of people who do optics. There are a lot who do nanoscale electrical measurements," he said. "There are still not too many people who combine the two."

The custom rig gave the Rice researchers a measure of control over thermal and electrical properties that have stymied other investigators. The tips are cooled to 80 Kelvin, about -315 degrees Fahrenheit, and are electrically insulated from their silicon bases, keeping at bay stray voltages that could skew the results.

"The reason we're studying these enhanced fields is not just because they're there," Natelson said. "If you can enhance the local field by a factor of 1,000, there are lots of things you can do in terms of sensors and non-linear optics. Anything that gives you a handle on what's happening at these tiny scales is very useful.

"This is one of those rare, happy cases where you are able to actually get information -- very local information -- about exactly something you care about."

The paper's co-authors are Falco Hüser and Fabian Pauly of the Karlsruhe Institute of Technology, Germany; and Juan Carlos Cuevas at the Autonomous University of Madrid, Spain.

Support for the project came from the Robert A. Welch Foundation, the Lockheed Martin Advanced Nanotechnology Center of Excellence at Rice (LANCER), Deutsche Forschungsgemeinschaft, the Baden-Württemberg Siftung, the European Union through the Bio-Inspired Approaches for Molecular Electronics (BIMORE) network, and the Spanish Ministry of Science and Innovation.

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Geckos Inspire New Method to Print Electronics on Complex Surfaces

Geckos Inspire New Method to Print Electronics on Complex Surfaces

  11:49:00 AM    Science Lover

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Geckos are masters at sticking to surfaces of all kinds and easily unsticking themselves, too. Inspired by these lizards, a team of engineers has developed a reversible adhesion method for printing electronics on a variety of tricky surfaces such as clothes, plastic and leather.

Gecko feet clinging on glass. Geckos are masters at sticking to surfaces of all kinds and easily unsticking themselves, too. Inspired by these lizards, a team of engineers has developed a reversible adhesion method for printing electronics on a variety of tricky surfaces such as clothes, plastic and leather. (Credit: iStockphoto/Stephan Hoerold)

Researchers from Northwestern University and the University of Illinois at Urbana-Champaign designed a clever square polymer stamp that allows them to vary its adhesion strength. The stamp can easily pick up an array of electronic devices from a silicon surface and move and print them on a curved surface.

The research will be published Sept. 20 by the Proceedings of the National Academy of Sciences (PNAS).

"Our work proposes a very robust method to transfer and print electronics on complex surfaces," said Yonggang Huang, Joseph Cummings Professor of Civil and Environmental Engineering and Mechanical Engineering at Northwestern's McCormick School of Engineering and Applied Science.

Huang, co-corresponding author of the PNAS paper, led the theory and design work at Northwestern. His colleague John Rogers, the Flory-Founder Chair Professor of Materials Science and Engineering at the University of Illinois, led the experimental and fabrication work. Rogers is a co-corresponding author of the paper.

Key to the square and squeezable polymer stamp are four pyramid-shaped tips on the stamp's bottom, one in each corner. They mimic, in a way, the micro- and nano-filaments on the gecko's foot, which the animal uses to control adhesion by increasing or decreasing contact area with a surface.

Pressing the stamp against the electronics causes the soft tips to collapse up against the stamp's body, maximizing the contact area between the stamp and the electronics and creating adhesion. The electronics are picked up in a complete batch, and, with the force removed, the soft tips snap back to their original shape. The electronics now are held in place by just the four tips, a small contact area. This allows the electronics to be easily transferred to a new surface.

"Design of the pyramid tips is very important," Huang said. "The tips have to be the right height. If the tips are too large, they can't pick up the target, and if the tips are too small, they won't bounce back to their shape."

The researchers conducted tests of the stamp and found the changes in contact area allow the stamp's adhesion strength to vary by 1,000 times. They also demonstrated their method can print layers of electronics, enabling the development of a variety of complex devices.

The National Science Foundation and the U.S. Department of Energy supported the work.

The title of the PNAS paper is "Microstructured Elastomeric Surfaces with Reversible Adhesion and Examples of Their Use in Deterministic Assembly by Transfer Printing." In addition to Huang and Rogers, other authors of the paper are Jian Wu (a postdoctoral fellow at Northwestern), Seok Kim, Andrew Carlson, Sung Hun Jin, Anton Kovalsky, Paul Glass, Zhuangjian Liu, Numair Ahmed, Steven L. Elgan, Weiqiu Chen, Placid M. Ferreira and Metin Sitti.

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Silicon Oxide Circuits Break BarrierNanocrystal Conductors Could Lead to Massive, Robust 3-D Storage

Silicon Oxide Circuits Break BarrierNanocrystal Conductors Could Lead to Massive, Robust 3-D Storage

  8:13:00 PM    Science Lover

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Rice University scientists have created the first two-terminal memory chips that use only silicon, one of the most common substances on the planet, in a way that should be easily adaptable to nanoelectronic manufacturing techniques and promises to extend the limits of miniaturization subject to Moore's Law.

A 1k silicon oxide memory has been assembled by Rice and a commercial partner as a proof-of-concept. Silicon nanowire forms when charge is pumped through the silicon oxide, creating a two-terminal resistive switch. (Credit: Images courtesy Jun Yao/Rice University)

Last year, researchers in the lab of Rice Professor James Tour showed how electrical current could repeatedly break and reconnect 10-nanometer strips of graphite, a form of carbon, to create a robust, reliable memory "bit." At the time, they didn't fully understand why it worked so well.

Now, they do. A new collaboration by the Rice labs of professors Tour, Douglas Natelson and Lin Zhong proved the circuit doesn't need the carbon at all.

Jun Yao, a graduate student in Tour's lab and primary author of the paper to appear in the online edition of Nano Letters, confirmed his breakthrough idea when he sandwiched a layer of silicon oxide, an insulator, between semiconducting sheets of polycrystalline silicon that served as the top and bottom electrodes.

Applying a charge to the electrodes created a conductive pathway by stripping oxygen atoms from the silicon oxide and forming a chain of nano-sized silicon crystals. Once formed, the chain can be repeatedly broken and reconnected by applying a pulse of varying voltage.

The nanocrystal wires are as small as 5 nanometers (billionths of a meter) wide, far smaller than circuitry in even the most advanced computers and electronic devices.

"The beauty of it is its simplicity," said Tour, Rice's T.T. and W.F. Chao Chair in Chemistry as well as a professor of mechanical engineering and materials science and of computer science. That, he said, will be key to the technology's scalability. Silicon oxide switches or memory locations require only two terminals, not three (as in flash memory), because the physical process doesn't require the device to hold a charge.

It also means layers of silicon-oxide memory can be stacked in tiny but capacious three-dimensional arrays. "I've been told by industry that if you're not in the 3-D memory business in four years, you're not going to be in the memory business. This is perfectly suited for that," Tour said.

Silicon-oxide memories are compatible with conventional transistor manufacturing technology, said Tour, who recently attended a workshop by the National Science Foundation and IBM on breaking the barriers to Moore's Law, which states the number of devices on a circuit doubles every 18 to 24 months.

"Manufacturers feel they can get pathways down to 10 nanometers. Flash memory is going to hit a brick wall at about 20 nanometers. But how do we get beyond that? Well, our technique is perfectly suited for sub-10-nanometer circuits," he said.

Austin tech design company PrivaTran is already bench testing a silicon-oxide chip with 1,000 memory elements built in collaboration with the Tour lab. "We're real excited about where the data is going here," said PrivaTran CEO Glenn Mortland, who is using the technology in several projects supported by the Army Research Office, National Science Foundation, Air Force Office of Scientific Research, and the Navy Space and Naval Warfare Systems Command Small Business Innovation Research (SBIR) and Small Business Technology Transfer programs.

"Our original customer funding was geared toward more high-density memories," Mortland said. "That's where most of the paying customers see this going. I think, along the way, there will be side applications in various nonvolatile configurations."

Yao had a hard time convincing his colleagues that silicon oxide alone could make a circuit. "Other group members didn't believe him," said Tour, who added that nobody recognized silicon oxide's potential, even though it's "the most-studied material in human history."

"Most people, when they saw this effect, would say, 'Oh, we had silicon-oxide breakdown,' and they throw it out," he said. "It was just sitting there waiting to be exploited."

In other words, what used to be a bug turned out to be a feature.

Yao went to the mat for his idea. He first substituted a variety of materials for graphite and found none of them changed the circuit's performance. Then he dropped the carbon and metal entirely and sandwiched silicon oxide between silicon terminals. It worked.

"It was a really difficult time for me, because people didn't believe it," Yao said. Finally, as a proof of concept, he cut a carbon nanotube to localize the switching site, sliced out a very thin piece of silicon oxide by focused ion beam and identified a nanoscale silicon pathway under a transmission electron microscope.

"This is research," Yao said. "If you do something and everyone nods their heads, then it's probably not that big. But if you do something and everyone shakes their heads, then you prove it, it could be big.

"It doesn't matter how many people don't believe it. What matters is whether it's true or not."

Silicon-oxide circuits carry all the benefits of the previously reported graphite device. They feature high on-off ratios, excellent endurance and fast switching (below 100 nanoseconds).

They will also be resistant to radiation, which should make them suitable for military and NASA applications. "It's clear there are lots of radiation-hardened uses for this technology," Mortland said.

Silicon oxide also works in reprogrammable gate arrays being built by NuPGA, a company formed last year through collaborative patents with Rice University. NuPGA's devices will assist in the design of computer circuitry based on vertical arrays of silicon oxide embedded in "vias," the holes in integrated circuits that connect layers of circuitry. Such rewritable gate arrays could drastically cut the cost of designing complex electronic devices.

Zhengzong Sun, a graduate student in Tour's lab, was co-author of the paper with Yao; Tour; Natelson, a Rice professor of physics and astronomy; and Zhong, assistant professor of electrical and computer engineering.

The David and Lucille Packard Foundation, the Texas Instruments Leadership University Fund, the National Science Foundation, PrivaTran and the Army Research Office SBIR supported the research.

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