Small in Size, Big On Power: New Microbatteries the Most Powerful Yet

Small in Size, Big On Power: New Microbatteries the Most Powerful Yet

  9:32:00 AM    Science Lover

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Though they be but little, they are fierce. The most powerful batteries on the planet are only a few millimeters in size, yet they pack such a punch that a driver could use a cellphone powered by these batteries to jump-start a dead car battery -- and then recharge the phone in the blink of an eye. 

The graphic illustrates a high power battery technology from the University of Illinois. Ions flow between three-dimensional micro-electrodes in a lithium ion battery. (Credit: Image courtesy of the Beckman Institute for Advanced Science and Technology)

Developed by researchers at the University of Illinois at Urbana-Champaign, the new microbatteries out-power even the best supercapacitors and could drive new applications in radio communications and compact electronics.

Led by William P. King, the Bliss Professor of mechanical science and engineering, the researchers published their results in the April 16 issue of Nature Communications.

"This is a whole new way to think about batteries," King said. "A battery can deliver far more power than anybody ever thought. In recent decades, electronics have gotten small. The thinking parts of computers have gotten small. And the battery has lagged far behind. This is a microtechnology that could change all of that. Now the power source is as high-performance as the rest of it."

With currently available power sources, users have had to choose between power and energy. For applications that need a lot of power, like broadcasting a radio signal over a long distance, capacitors can release energy very quickly but can only store a small amount. For applications that need a lot of energy, like playing a radio for a long time, fuel cells and batteries can hold a lot of energy but release it or recharge slowly.

"There's a sacrifice," said James Pikul, a graduate student and first author of the paper. "If you want high energy you can't get high power; if you want high power it's very difficult to get high energy. But for very interesting applications, especially modern applications, you really need both. That's what our batteries are starting to do. We're really pushing into an area in the energy storage design space that is not currently available with technologies today."

The new microbatteries offer both power and energy, and by tweaking the structure a bit, the researchers can tune them over a wide range on the power-versus-energy scale.

The batteries owe their high performance to their internal three-dimensional microstructure. Batteries have two key components: the anode (minus side) and cathode (plus side). Building on a novel fast-charging cathode design by materials science and engineering professor Paul Braun's group, King and Pikul developed a matching anode and then developed a new way to integrate the two components at the microscale to make a complete battery with superior performance.

With so much power, the batteries could enable sensors or radio signals that broadcast 30 times farther, or devices 30 times smaller. The batteries are rechargeable and can charge 1,000 times faster than competing technologies -- imagine juicing up a credit-card-thin phone in less than a second. In addition to consumer electronics, medical devices, lasers, sensors and other applications could see leaps forward in technology with such power sources available.

"Any kind of electronic device is limited by the size of the battery -- until now," King said. "Consider personal medical devices and implants, where the battery is an enormous brick, and it's connected to itty-bitty electronics and tiny wires. Now the battery is also tiny."

Now, the researchers are working on integrating their batteries with other electronics components, as well as manufacturability at low cost.

"Now we can think outside of the box," Pikul said. "It's a new enabling technology. It's not a progressive improvement over previous technologies; it breaks the normal paradigms of energy sources. It's allowing us to do different, new things."

The National Science Foundation and the Air Force Office of Scientific Research supported this work. King also is affiliated with the Beckman Institute for Advanced Science and Technology; the Frederick Seitz Materials Research Laboratory; the Micro and Nanotechnology Laboratory; and the department of electrical and computer engineering at the U. of I.

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Electricity and Carbon Dioxide Used to Generate Alternative Fuel

Electricity and Carbon Dioxide Used to Generate Alternative Fuel

  8:10:00 PM    Science Lover

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Imagine being able to use electricity to power your car -- even if it's not an electric vehicle. Researchers at the UCLA Henry Samueli School of Engineering and Applied Science have for the first time demonstrated a method for converting carbon dioxide into liquid fuel isobutanol using electricity.

Producing fuel from CO2 and sunlight. (Credit: Image
courtesy of University of California - Los Angeles)

Today, electrical energy generated by various methods is still difficult to store efficiently. Chemical batteries, hydraulic pumping and water splitting suffer from low energy-density storage or incompatibility with current transportation infrastructure.

In a study published March 30 in the journal Science, James Liao, UCLA's Ralph M. Parsons Foundation Chair in Chemical Engineering, and his team report a method for storing electrical energy as chemical energy in higher alcohols, which can be used as liquid transportation fuels.

"The current way to store electricity is with lithium ion batteries, in which the density is low, but when you store it in liquid fuel, the density could actually be very high," Liao said. "In addition, we have the potential to use electricity as transportation fuel without needing to change current infrastructure."

Liao and his team genetically engineered a lithoautotrophic microorganism known as Ralstonia eutropha H16 to produce isobutanol and 3-methyl-1-butanol in an electro-bioreactor using carbon dioxide as the sole carbon source and electricity as the sole energy input.

Photosynthesis is the process of converting light energy to chemical energy and storing it in the bonds of sugar. There are two parts to photosynthesis -- a light reaction and a dark reaction. The light reaction converts light energy to chemical energy and must take place in the light. The dark reaction, which converts CO2 to sugar, doesn't directly need light to occur.

"We've been able to separate the light reaction from the dark reaction and instead of using biological photosynthesis, we are using solar panels to convert the sunlight to electrical energy, then to a chemical intermediate, and using that to power carbon dioxide fixation to produce the fuel," Liao said. "This method could be more efficient than the biological system."

Liao explained that with biological systems, the plants used require large areas of agricultural land. However, because Liao's method does not require the light and dark reactions to take place together, solar panels, for example, can be built in the desert or on rooftops.

Theoretically, the hydrogen generated by solar electricity can drive CO2 conversion in lithoautotrophic microorganisms engineered to synthesize high-energy density liquid fuels. But the low solubility, low mass-transfer rate and the safety issues surrounding hydrogen limit the efficiency and scalability of such processes. Instead Liao's team found formic acid to be a favorable substitute and efficient energy carrier.

"Instead of using hydrogen, we use formic acid as the intermediary," Liao said. "We use electricity to generate formic acid and then use the formic acid to power the CO2 fixation in bacteria in the dark to produce isobutanol and higher alcohols."

The electrochemical formate production and the biological CO2 fixation and higher alcohol synthesis now open up the possibility of electricity-driven bioconversion of CO2 to a variety of chemicals. In addition, the transformation of formate into liquid fuel will also play an important role in the biomass refinery process, according to Liao.

"We've demonstrated the principle, and now we think we can scale up," he said. "That's our next step."

The study was funded by a grant from the U.S. Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E).

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New Way to Store Sun's Heat: Modified Carbon Nanotubes Can Store Solar Energy Indefinitely, Then Be Recharged by Exposure to the Sun

New Way to Store Sun's Heat: Modified Carbon Nanotubes Can Store Solar Energy Indefinitely, Then Be Recharged by Exposure to the Sun

  12:25:00 AM    Science Lover

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A novel application of carbon nanotubes, developed by MIT researchers, shows promise as an innovative approach to storing solar energy for use whenever it's needed.

Illustration. (Credit: Image courtesy of Grossman/Kolpak)

Storing the sun's heat in chemical form -- rather than converting it to electricity or storing the heat itself in a heavily insulated container -- has significant advantages, since in principle the chemical material can be stored for long periods of time without losing any of its stored energy. The problem with that approach has been that until now the chemicals needed to perform this conversion and storage either degraded within a few cycles, or included the element ruthenium, which is rare and expensive.

Last year, MIT associate professor Jeffrey Grossman and four co-authors figured out exactly how fulvalene diruthenium -- known to scientists as the best chemical for reversibly storing solar energy, since it did not degrade -- was able to accomplish this feat. Grossman said at the time that better understanding this process could make it easier to search for other compounds, made of abundant and inexpensive materials, which could be used in the same way.

Now, he and postdoc Alexie Kolpak have succeeded in doing just that. A paper describing their new findings has just been published online in the journal Nano Letters, and will appear in print in a forthcoming issue.

The new material found by Grossman and Kolpak is made using carbon nanotubes, tiny tubular structures of pure carbon, in combination with a compound called azobenzene. The resulting molecules, produced using nanoscale templates to shape and constrain their physical structure, gain "new properties that aren't available" in the separate materials, says Grossman, the Carl Richard Soderberg Associate Professor of Power Engineering.

Not only is this new chemical system less expensive than the earlier ruthenium-containing compound, but it also is vastly more efficient at storing energy in a given amount of space -- about 10,000 times higher in volumetric energy density, Kolpak says -- making its energy density comparable to lithium-ion batteries. By using nanofabrication methods, "you can control [the molecules'] interactions, increasing the amount of energy they can store and the length of time for which they can store it -- and most importantly, you can control both independently," she says.

Thermo-chemical storage of solar energy uses a molecule whose structure changes when exposed to sunlight, and can remain stable in that form indefinitely. Then, when nudged by a stimulus -- a catalyst, a small temperature change, a flash of light -- it can quickly snap back to its other form, releasing its stored energy in a burst of heat. Grossman describes it as creating a rechargeable heat battery with a long shelf life, like a conventional battery.



One of the great advantages of the new approach to harnessing solar energy, Grossman says, is that it simplifies the process by combining energy harvesting and storage into a single step. "You've got a material that both converts and stores energy," he says. "It's robust, it doesn't degrade, and it's cheap." One limitation, however, is that while this process is useful for heating applications, to produce electricity would require another conversion step, using thermoelectric devices or producing steam to run a generator.

While the new work shows the energy-storage capability of a specific type of molecule -- azobenzene-functionalized carbon nanotubes -- Grossman says the way the material was designed involves "a general concept that can be applied to many new materials." Many of these have already been synthesized by other researchers for different applications, and would simply need to have their properties fine-tuned for solar thermal storage.

The key to controlling solar thermal storage is an energy barrier separating the two stable states the molecule can adopt; the detailed understanding of that barrier was central to Grossman's earlier research on fulvalene dirunthenium, accounting for its long-term stability. Too low a barrier, and the molecule would return too easily to its "uncharged" state, failing to store energy for long periods; if the barrier were too high, it would not be able to easily release its energy when needed. "The barrier has to be optimized," Grossman says.

Already, the team is "very actively looking at a range of new materials," he says. While they have already identified the one very promising material described in this paper, he says, "I see this as the tip of the iceberg. We're pretty jazzed up about it."

Yosuke Kanai, assistant professor of chemistry at the University of North Carolina at Chapel Hill, says "the idea of reversibly storing solar energy in chemical bonds is gaining a lot of attention these days. The novelty of this work is how these authors have shown that the energy density can be significantly increased by using carbon nanotubes as nanoscale templates. This innovative idea also opens up an interesting avenue for tailoring already-known photoactive molecules for solar thermal fuels and storage in general."

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Power from the Air: Device Captures Ambient Electromagnetic Energy to Drive Small Electronic Devices

Power from the Air: Device Captures Ambient Electromagnetic Energy to Drive Small Electronic Devices

  8:44:00 PM    Science Lover

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Researchers have discovered a way to capture and harness energy transmitted by such sources as radio and television transmitters, cell phone networks and satellite communications systems. By scavenging this ambient energy from the air around us, the technique could provide a new way to power networks of wireless sensors, microprocessors and communications chips.

Georgia Tech School of Electrical and Computer Engineering
professor Manos Tentzeris holds a sensor (left) and an
ultra-broadband spiral antenna for wearable energy-
scavenging applications. Both were printed on paper using
inkjet technology. (Credit: Georgia Tech Photo: Gary Meek)

"There is a large amount of electromagnetic energy all around us, but nobody has been able to tap into it," said Manos Tentzeris, a professor in the Georgia Tech School of Electrical and Computer Engineering who is leading the research. "We are using an ultra-wideband antenna that lets us exploit a variety of signals in different frequency ranges, giving us greatly increased power-gathering capability."

Tentzeris and his team are using inkjet printers to combine sensors, antennas and energy scavenging capabilities on paper or flexible polymers. The resulting self powered wireless sensors could be used for chemical, biological, heat and stress sensing for defense and industry; radio frequency identification (RFID) tagging for manufacturing and shipping, and monitoring tasks in many fields including communications and power usage.

A presentation on this energy scavenging technology was given July 6 at the IEEE Antennas and Propagation Symposium in Spokane, Wash. The discovery is based on research supported by multiple sponsors, including the National Science Foundation, the Federal Highway Administration and Japan's New Energy and Industrial Technology Development Organization (NEDO).

Communications devices transmit energy in many different frequency ranges, or bands. The team's scavenging devices can capture this energy, convert it from AC to DC, and then store it in capacitors and batteries. The scavenging technology can take advantage presently of frequencies from FM radio to radar, a range spanning 100 megahertz (MHz) to 15 gigahertz (GHz) or higher.

Scavenging experiments utilizing TV bands have already yielded power amounting to hundreds of microwatts, and multi-band systems are expected to generate one milliwatt or more. That amount of power is enough to operate many small electronic devices, including a variety of sensors and microprocessors.

And by combining energy scavenging technology with supercapacitors and cycled operation, the Georgia Tech team expects to power devices requiring above 50 milliwatts. In this approach, energy builds up in a battery-like supercapacitor and is utilized when the required power level is reached.

The researchers have already successfully operated a temperature sensor using electromagnetic energy captured from a television station that was half a kilometer distant. They are preparing another demonstration in which a microprocessor-based microcontroller would be activated simply by holding it in the air.

Exploiting a range of electromagnetic bands increases the dependability of energy scavenging devices, explained Tentzeris, who is also a faculty researcher in the Georgia Electronic Design Center at Georgia Tech. If one frequency range fades temporarily due to usage variations, the system can still exploit other frequencies.

The scavenging device could be used by itself or in tandem with other generating technologies. For example, scavenged energy could assist a solar element to charge a battery during the day. At night, when solar cells don't provide power, scavenged energy would continue to increase the battery charge or would prevent discharging.

Utilizing ambient electromagnetic energy could also provide a form of system backup. If a battery or a solar-collector/battery package failed completely, scavenged energy could allow the system to transmit a wireless distress signal while also potentially maintaining critical functionalities.

The researchers are utilizing inkjet technology to print these energy scavenging devices on paper or flexible paper-like polymers -- a technique they already using to produce sensors and antennas. The result would be paper-based wireless sensors that are self powered, low cost and able to function independently almost anywhere.



To print electrical components and circuits, the Georgia Tech researchers use a standard materials inkjet printer. However, they add what Tentzeris calls "a unique in house recipe" containing silver nanoparticles and/or other nanoparticles in an emulsion. This approach enables the team to print not only RF components and circuits, but also novel sensing devices based on such nanomaterials as carbon nanotubes.

When Tentzeris and his research group began inkjet printing of antennas in 2006, the paper-based circuits only functioned at frequencies of 100 or 200 MHz, recalled Rushi Vyas, a graduate student who is working with Tentzeris and graduate student Vasileios Lakafosis on several projects.

"We can now print circuits that are capable of functioning at up to 15 GHz -- 60 GHz if we print on a polymer," Vyas said. "So we have seen a frequency operation improvement of two orders of magnitude."

The researchers believe that self-powered, wireless paper-based sensors will soon be widely available at very low cost. The resulting proliferation of autonomous, inexpensive sensors could be used for applications that include:

• Airport security: Airports have both multiple security concerns and vast amounts of available ambient energy from radar and communications sources. These dual factors make them a natural environment for large numbers of wireless sensors capable of detecting potential threats such as explosives or smuggled nuclear material.
• Energy savings: Self-powered wireless sensing devices placed throughout a home could provide continuous monitoring of temperature and humidity conditions, leading to highly significant savings on heating and air conditioning costs. And unlike many of today's sensing devices, environmentally friendly paper-based sensors would degrade quickly in landfills.
• Structural integrity: Paper or polymer-based sensors could be placed throughout various types of structures to monitor stress. Self powered sensors on buildings, bridges or aircraft could quietly watch for problems, perhaps for many years, and then transmit a signal when they detected an unusual condition.
• Food and perishable material storage and quality monitoring: Inexpensive sensors on foods could scan for chemicals that indicate spoilage and send out an early warning if they encountered problems.
• Wearable bio-monitoring devices: This emerging wireless technology could become widely used for autonomous observation of patient medical issues.

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Glitter-Sized Solar Photovoltaics Could Revolutionize the Way Solar Energy Is Collected and Used

Glitter-Sized Solar Photovoltaics Could Revolutionize the Way Solar Energy Is Collected and Used

  1:21:00 AM    Science Lover

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Sandia National Laboratories scientists have developed tiny glitter-sized photovoltaic cells that could revolutionize the way solar energy is collected and used.

Representative thin crystalline-silicon photovoltaic cells -- these are from 14 to 20 micrometers thick and 0.25 to 1 millimeter across. (Credit: Image by Murat Okandan)

The tiny cells could turn a person into a walking solar battery charger if they were fastened to flexible substrates molded around unusual shapes, such as clothing.

The solar particles, fabricated of crystalline silicon, hold the potential for a variety of new applications. They are expected eventually to be less expensive and have greater efficiencies than current photovoltaic collectors that are pieced together with 6-inch- square solar wafers.

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