Sugar-powered biobattery has 10 times the energy storage of lithium: Your smartphone might soon run on enzymes

Sugar-powered biobattery has 10 times the energy storage of lithium: Your smartphone might soon run on enzymes

  7:33:00 PM    Science Lover

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As you probably know, from sucking down cans of Coke and masticating on candy, sugar — glucose, fructose, sucrose, dextrose — is an excellent source of energy. Biologically speaking, sugar molecules are energy-dense, easy to transport, and cheap to digest. There is a reason why almost every living cell on Earth generates its energy (ATP) from glucose. Now, researchers at Virginia Tech have successfully created a sugar-powered fuel cell that has an energy storage density of 596 amp-hours per kilo — or “one order of magnitude” higher than lithium-ion batteries. This fuel cell is refillable with a solution of maltodextrin, and its only by products are electricity and water. The chief researcher, Y.H. Percival Zhang, says the tech could be commercialized in as soon as three years.

Now, it’s not exactly news that sugar is an excellent energy source. As a culture we’ve probably known about it since before we were Homo sapiens. The problem is, unless you’re a living organism or some kind of incendiary device, extracting that energy is difficult. In nature, an enzymatic pathway is used — a production line of tailor-made enzymes that meddle with the glucose molecules until they become ATP. Because it’s easy enough to produce enzymes in large quantities, researchers have tried to create fuel cells that use artificial “metabolism” to break down glucose into electricity (biobatteries), but it has historically proven very hard to find the right pathway for maximum efficiency and to keep the enzymes in the right place over a long period of time.

A diagram of the enzymatic fuel cell. The little Pac-Man things are enzymes.

Now, however, Zhang and friends at Virginia Tech appear to have built a high-density fuel cell that uses an enzymatic pathway to create a lot of electricity from glucose. There doesn’t seem to be much information on how stable this biobattery is over multiple refills, but if Zhang thinks it could be commercialized in three years, that’s a very good sign. Curiously, the research paper says that the enzymes are non-immobilized — meaning Zhang found a certain battery chemistry that doesn’t require the enzymes to be kept in place… or, alternatively, that it will only work for a very short time.

The Virginia Tech biobattery uses 13 enzymes, plus air (it’s an air-breathing biobattery), to produce nearly 24 electrons from a single glucose unit. This equates to a power output of 0.8 mW/cm, current density of 6 mA/cm, and energy storage density of 596 Ah/kg. This last figure is impressive, at roughly 10 times the energy density of the lithium-ion batteries in your mobile devices. [Research paper: doi:10.1038/ncomms4026 - "A high-energy-density sugar biobattery based on a synthetic enzymatic pathway"]

If Zhang’s biobatteries pan out, you might soon be recharging your smartphone by pouring in a solution of 15% maltodextrin. That battery would not only be very safe (it produces water and electricity), but very cheap to run and very green. This seems to fit in perfectly with Zhang’s homepage, which talks about how his main goals in life are replacing crude oil with sugar, and feeding the world.

The other area in which biobatteries might be useful is powering implanted devices, such as pacemakers — or, in the future, subcutaneous sensors and computers. Such a biobattery could feed on the glucose in your bloodstream, providing an endless supply of safe electricity for the myriad implants that futuristic technocrats will surely have. 

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A Battery Made of Wood?

A Battery Made of Wood?

  9:04:00 AM    Science Lover

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A sliver of wood coated with tin could make a tiny, long-lasting, efficient and environmentally friendly battery.

Close-up image of wood fibers. "Wood fibers that make up a tree once held mineral-rich water, and so are ideal for storing liquid electrolytes, making them not only the base but an active part of the battery," Liangbing Hu said. (Credit: Image courtesy of University of Maryland)

But don't try it at home yet -- the components in the battery tested by scientists at the University of Maryland are a thousand times thinner than a piece of paper. Using sodium instead of lithium, as many rechargeable batteries do, makes the battery environmentally benign. Sodium doesn't store energy as efficiently as lithium, so you won't see this battery in your cell phone -- instead, its low cost and common materials would make it ideal to store huge amounts of energy at once, such as solar energy at a power plant.

Existing batteries are often created on stiff bases, which are too brittle to withstand the swelling and shrinking that happens as electrons are stored in and used up from the battery. Liangbing Hu, Teng Li and their team found that wood fibers are supple enough to let their sodium-ion battery last more than 400 charging cycles, which puts it among the longest lasting nanobatteries.

"The inspiration behind the idea comes from the trees," said Hu, an assistant professor of materials science. "Wood fibers that make up a tree once held mineral-rich water, and so are ideal for storing liquid electrolytes, making them not only the base but an active part of the battery."

Lead author Hongli Zhu and other team members noticed that after charging and discharging the battery hundreds of times, the wood ended up wrinkled but intact. Computer models showed that that the wrinkles effectively relax the stress in the battery during charging and recharging, so that the battery can survive many cycles.

"Pushing sodium ions through tin anodes often weaken the tin's connection to its base material," said Li, an associate professor of mechanical engineering. "But the wood fibers are soft enough to serve as a mechanical buffer, and thus can accommodate tin's changes. This is the key to our long-lasting sodium-ion batteries."

The team's research was supported by the University of Maryland and the U.S. National Science Foundation.

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Small in Size, Big On Power: New Microbatteries the Most Powerful Yet

Small in Size, Big On Power: New Microbatteries the Most Powerful Yet

  9:32:00 AM    Science Lover

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Though they be but little, they are fierce. The most powerful batteries on the planet are only a few millimeters in size, yet they pack such a punch that a driver could use a cellphone powered by these batteries to jump-start a dead car battery -- and then recharge the phone in the blink of an eye. 

The graphic illustrates a high power battery technology from the University of Illinois. Ions flow between three-dimensional micro-electrodes in a lithium ion battery. (Credit: Image courtesy of the Beckman Institute for Advanced Science and Technology)

Developed by researchers at the University of Illinois at Urbana-Champaign, the new microbatteries out-power even the best supercapacitors and could drive new applications in radio communications and compact electronics.

Led by William P. King, the Bliss Professor of mechanical science and engineering, the researchers published their results in the April 16 issue of Nature Communications.

"This is a whole new way to think about batteries," King said. "A battery can deliver far more power than anybody ever thought. In recent decades, electronics have gotten small. The thinking parts of computers have gotten small. And the battery has lagged far behind. This is a microtechnology that could change all of that. Now the power source is as high-performance as the rest of it."

With currently available power sources, users have had to choose between power and energy. For applications that need a lot of power, like broadcasting a radio signal over a long distance, capacitors can release energy very quickly but can only store a small amount. For applications that need a lot of energy, like playing a radio for a long time, fuel cells and batteries can hold a lot of energy but release it or recharge slowly.

"There's a sacrifice," said James Pikul, a graduate student and first author of the paper. "If you want high energy you can't get high power; if you want high power it's very difficult to get high energy. But for very interesting applications, especially modern applications, you really need both. That's what our batteries are starting to do. We're really pushing into an area in the energy storage design space that is not currently available with technologies today."

The new microbatteries offer both power and energy, and by tweaking the structure a bit, the researchers can tune them over a wide range on the power-versus-energy scale.

The batteries owe their high performance to their internal three-dimensional microstructure. Batteries have two key components: the anode (minus side) and cathode (plus side). Building on a novel fast-charging cathode design by materials science and engineering professor Paul Braun's group, King and Pikul developed a matching anode and then developed a new way to integrate the two components at the microscale to make a complete battery with superior performance.

With so much power, the batteries could enable sensors or radio signals that broadcast 30 times farther, or devices 30 times smaller. The batteries are rechargeable and can charge 1,000 times faster than competing technologies -- imagine juicing up a credit-card-thin phone in less than a second. In addition to consumer electronics, medical devices, lasers, sensors and other applications could see leaps forward in technology with such power sources available.

"Any kind of electronic device is limited by the size of the battery -- until now," King said. "Consider personal medical devices and implants, where the battery is an enormous brick, and it's connected to itty-bitty electronics and tiny wires. Now the battery is also tiny."

Now, the researchers are working on integrating their batteries with other electronics components, as well as manufacturability at low cost.

"Now we can think outside of the box," Pikul said. "It's a new enabling technology. It's not a progressive improvement over previous technologies; it breaks the normal paradigms of energy sources. It's allowing us to do different, new things."

The National Science Foundation and the Air Force Office of Scientific Research supported this work. King also is affiliated with the Beckman Institute for Advanced Science and Technology; the Frederick Seitz Materials Research Laboratory; the Micro and Nanotechnology Laboratory; and the department of electrical and computer engineering at the U. of I.

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New Energy Source for Future Medical Implants: Sugar

New Energy Source for Future Medical Implants: Sugar

  7:50:00 PM    Science Lover

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MIT engineers have developed a fuel cell that runs on the same sugar that powers human cells: glucose. This glucose fuel cell could be used to drive highly efficient brain implants of the future, which could help paralyzed patients move their arms and legs again.

This silicon wafer consists of glucose fuel cells of varying sizes; 
the largest is 64 by 64 mm. Image: (Credit: Sarpeshkar Lab)

The fuel cell, described in the June 12 edition of the journal PLoS ONE, strips electrons from glucose molecules to create a small electric current. The researchers, led by Rahul Sarpeshkar, an associate professor of electrical engineering and computer science at MIT, fabricated the fuel cell on a silicon chip, allowing it to be integrated with other circuits that would be needed for a brain implant.

The idea of a glucose fuel cell is not new: In the 1970s, scientists showed they could power a pacemaker with a glucose fuel cell, but the idea was abandoned in favor of lithium-ion batteries, which could provide significantly more power per unit area than glucose fuel cells. These glucose fuel cells also utilized enzymes that proved to be impractical for long-term implantation in the body, since they eventually ceased to function efficiently.

The new twist to the MIT fuel cell described in PLoS ONE is that it is fabricated from silicon, using the same technology used to make semiconductor electronic chips. The fuel cell has no biological components: It consists of a platinum catalyst that strips electrons from glucose, mimicking the activity of cellular enzymes that break down glucose to generate ATP, the cell's energy currency. (Platinum has a proven record of long-term biocompatibility within the body.) So far, the fuel cell can generate up to hundreds of microwatts -- enough to power an ultra-low-power and clinically useful neural implant.

"It will be a few more years into the future before you see people with spinal-cord injuries receive such implantable systems in the context of standard medical care, but those are the sorts of devices you could envision powering from a glucose-based fuel cell," says Benjamin Rapoport, a former graduate student in the Sarpeshkar lab and the first author on the new MIT study.

Rapoport calculated that in theory, the glucose fuel cell could get all the sugar it needs from the cerebrospinal fluid (CSF) that bathes the brain and protects it from banging into the skull. There are very few cells in the CSF, so it's highly unlikely that an implant located there would provoke an immune response. There is also significant glucose in the CSF, which does not generally get used by the body. Since only a small fraction of the available power is utilized by the glucose fuel cell, the impact on the brain's function would likely be small.

Karim Oweiss, an associate professor of electrical engineering, computer science and neuroscience at Michigan State University, says the work is a good step toward developing implantable medical devices that don't require external power sources.

"It's a proof of concept that they can generate enough power to meet the requirements," says Oweiss, adding that the next step will be to demonstrate that it can work in a living animal.

A team of researchers at Brown University, Massachusetts General Hospital and other institutions recently demonstrated that paralyzed patients could use a brain-machine interface to move a robotic arm; those implants have to be plugged into a wall outlet.

Mimicking biology with microelectronics

Sarpeshkar's group is a leader in the field of ultra-low-power electronics, having pioneered such designs for cochlear implants and brain implants. "The glucose fuel cell, when combined with such ultra-low-power electronics, can enable brain implants or other implants to be completely self-powered," says Sarpeshkar, author of the book "Ultra Low Power Bioelectronics." This book discusses how the combination of ultra-low-power and energy-harvesting design can enable self-powered devices for medical, bio-inspired and portable applications.

Sarpeshkar's group has worked on all aspects of implantable brain-machine interfaces and neural prosthetics, including recording from nerves, stimulating nerves, decoding nerve signals and communicating wirelessly with implants. One such neural prosthetic is designed to record electrical activity from hundreds of neurons in the brain's motor cortex, which is responsible for controlling movement. That data is amplified and converted into a digital signal so that computers -- or in the Sarpeshkar team's work, brain-implanted microchips -- can analyze it and determine which patterns of brain activity produce movement.

The fabrication of the glucose fuel cell was done in collaboration with Jakub Kedzierski at MIT's Lincoln Laboratory. "This collaboration with Lincoln Lab helped make a long-term goal of mine -- to create glucose-powered bioelectronics -- a reality," Sarpeshkar says. Although he has just begun working on bringing ultra-low-power and medical technology to market, he cautions that glucose-powered implantable medical devices are still many years away.

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Power from the Air: Device Captures Ambient Electromagnetic Energy to Drive Small Electronic Devices

Power from the Air: Device Captures Ambient Electromagnetic Energy to Drive Small Electronic Devices

  8:44:00 PM    Science Lover

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Researchers have discovered a way to capture and harness energy transmitted by such sources as radio and television transmitters, cell phone networks and satellite communications systems. By scavenging this ambient energy from the air around us, the technique could provide a new way to power networks of wireless sensors, microprocessors and communications chips.

Georgia Tech School of Electrical and Computer Engineering
professor Manos Tentzeris holds a sensor (left) and an
ultra-broadband spiral antenna for wearable energy-
scavenging applications. Both were printed on paper using
inkjet technology. (Credit: Georgia Tech Photo: Gary Meek)

"There is a large amount of electromagnetic energy all around us, but nobody has been able to tap into it," said Manos Tentzeris, a professor in the Georgia Tech School of Electrical and Computer Engineering who is leading the research. "We are using an ultra-wideband antenna that lets us exploit a variety of signals in different frequency ranges, giving us greatly increased power-gathering capability."

Tentzeris and his team are using inkjet printers to combine sensors, antennas and energy scavenging capabilities on paper or flexible polymers. The resulting self powered wireless sensors could be used for chemical, biological, heat and stress sensing for defense and industry; radio frequency identification (RFID) tagging for manufacturing and shipping, and monitoring tasks in many fields including communications and power usage.

A presentation on this energy scavenging technology was given July 6 at the IEEE Antennas and Propagation Symposium in Spokane, Wash. The discovery is based on research supported by multiple sponsors, including the National Science Foundation, the Federal Highway Administration and Japan's New Energy and Industrial Technology Development Organization (NEDO).

Communications devices transmit energy in many different frequency ranges, or bands. The team's scavenging devices can capture this energy, convert it from AC to DC, and then store it in capacitors and batteries. The scavenging technology can take advantage presently of frequencies from FM radio to radar, a range spanning 100 megahertz (MHz) to 15 gigahertz (GHz) or higher.

Scavenging experiments utilizing TV bands have already yielded power amounting to hundreds of microwatts, and multi-band systems are expected to generate one milliwatt or more. That amount of power is enough to operate many small electronic devices, including a variety of sensors and microprocessors.

And by combining energy scavenging technology with supercapacitors and cycled operation, the Georgia Tech team expects to power devices requiring above 50 milliwatts. In this approach, energy builds up in a battery-like supercapacitor and is utilized when the required power level is reached.

The researchers have already successfully operated a temperature sensor using electromagnetic energy captured from a television station that was half a kilometer distant. They are preparing another demonstration in which a microprocessor-based microcontroller would be activated simply by holding it in the air.

Exploiting a range of electromagnetic bands increases the dependability of energy scavenging devices, explained Tentzeris, who is also a faculty researcher in the Georgia Electronic Design Center at Georgia Tech. If one frequency range fades temporarily due to usage variations, the system can still exploit other frequencies.

The scavenging device could be used by itself or in tandem with other generating technologies. For example, scavenged energy could assist a solar element to charge a battery during the day. At night, when solar cells don't provide power, scavenged energy would continue to increase the battery charge or would prevent discharging.

Utilizing ambient electromagnetic energy could also provide a form of system backup. If a battery or a solar-collector/battery package failed completely, scavenged energy could allow the system to transmit a wireless distress signal while also potentially maintaining critical functionalities.

The researchers are utilizing inkjet technology to print these energy scavenging devices on paper or flexible paper-like polymers -- a technique they already using to produce sensors and antennas. The result would be paper-based wireless sensors that are self powered, low cost and able to function independently almost anywhere.



To print electrical components and circuits, the Georgia Tech researchers use a standard materials inkjet printer. However, they add what Tentzeris calls "a unique in house recipe" containing silver nanoparticles and/or other nanoparticles in an emulsion. This approach enables the team to print not only RF components and circuits, but also novel sensing devices based on such nanomaterials as carbon nanotubes.

When Tentzeris and his research group began inkjet printing of antennas in 2006, the paper-based circuits only functioned at frequencies of 100 or 200 MHz, recalled Rushi Vyas, a graduate student who is working with Tentzeris and graduate student Vasileios Lakafosis on several projects.

"We can now print circuits that are capable of functioning at up to 15 GHz -- 60 GHz if we print on a polymer," Vyas said. "So we have seen a frequency operation improvement of two orders of magnitude."

The researchers believe that self-powered, wireless paper-based sensors will soon be widely available at very low cost. The resulting proliferation of autonomous, inexpensive sensors could be used for applications that include:

• Airport security: Airports have both multiple security concerns and vast amounts of available ambient energy from radar and communications sources. These dual factors make them a natural environment for large numbers of wireless sensors capable of detecting potential threats such as explosives or smuggled nuclear material.
• Energy savings: Self-powered wireless sensing devices placed throughout a home could provide continuous monitoring of temperature and humidity conditions, leading to highly significant savings on heating and air conditioning costs. And unlike many of today's sensing devices, environmentally friendly paper-based sensors would degrade quickly in landfills.
• Structural integrity: Paper or polymer-based sensors could be placed throughout various types of structures to monitor stress. Self powered sensors on buildings, bridges or aircraft could quietly watch for problems, perhaps for many years, and then transmit a signal when they detected an unusual condition.
• Food and perishable material storage and quality monitoring: Inexpensive sensors on foods could scan for chemicals that indicate spoilage and send out an early warning if they encountered problems.
• Wearable bio-monitoring devices: This emerging wireless technology could become widely used for autonomous observation of patient medical issues.

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A cheaper, lighter and longer-lasting alternative to modern batteries

A cheaper, lighter and longer-lasting alternative to modern batteries

  9:56:00 PM    Science Lover

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MOBILE phones looked like bricks in the 1980s. Indeed, they were so cumbersome that most were installed in cars. That was because the batteries required to power them were so hefty. When lithium-ion batteries were invented, mobile phones became small enough to be carried in a pocket or slipped into a handbag. Now a new design of battery that uses oxygen from ambient air to power devices could provide even smaller and lighter sources of power. Not only that, such batteries would be cheaper and last for longer between charges.

Lithium-ion batteries have two electrodes immersed in an electrically conductive solution, called an electrolyte. One of the electrodes, the cathode, is made of lithium cobalt oxide; the other, the anode, is composed of carbon. When the battery is being charged, positively charged lithium ions break away from the cathode and travel in the electrolyte to the anode, where they meet electrons brought there by a charging device. When electricity is needed, the anode releases the lithium ions, which rapidly move back to the cathode. As they do so, the electrons that were paired with them in the anode during the charging process are released. These electrons travel around an external circuit to which the battery is attached and power it.

Peter Bruce and his colleagues at the University of St Andrews in Scotland came up with the idea of replacing the lithium cobalt oxide electrode with a cheaper and lighter alternative. They designed an electrode made from porous carbon and lithium oxide. They knew that lithium oxide forms naturally from lithium ions, electrons and oxygen, but, to their surprise, they found that it could also be made to separate easily when an electric current passed through it. They exposed one side of their porous carbon electrode to an electrolyte rich in lithium ions and put a mesh window on the other side of the electrode through which air could be drawn. Oxygen from the air took the place of the cobalt oxide.

When they charged their battery, the lithium ions migrated to the anode where they combined with electrons from the charging device. When they discharged it, lithium ions and electrons were released from the anode. The ions crossed the electrolyte and the electrons travelled round the external circuit. The ions and electrons then met at the cathode, where they combined with the oxygen to form lithium oxide that filled the pores in the carbon.

Because the oxygen being used by the battery comes from the surrounding air rather than having to be carried around inside the battery, the device that Dr Bruce’s team has designed can be a mere one-eighth to one-tenth the size and weight of modern batteries, while still carrying the same charge. Alternatively, batteries using the new technology would last eight to ten times longer than modern batteries of the same size.

Performance and size are not the only expected improvements. Although they are not yet commercially available, making such a battery is expected to be cheaper. Lithium cobalt oxide accounts for 30% of the cost of a lithium-ion battery. Air, however, is free.

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Air-fueled Battery Could Last Up To 10 Times Longer: Ground-breaking Technology For Electric Cars

Air-fueled Battery Could Last Up To 10 Times Longer: Ground-breaking Technology For Electric Cars

  9:55:00 AM    Science Lover

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A new type of air-fuelled battery could give up to ten times the energy storage of designs currently available.

Diagram of the STAIR (St Andrews Air) cell. Oxygen drawn from the air reacts within the porous carbon to release the electrical charge in this lithium-air battery. (Credit: Image courtesy of Engineering and Physical Sciences Research Council (EPSRC))

This step-change in capacity could pave the way for a new generation of electric cars, mobile phones and laptops.

The research work, funded by the Engineering and Physical Sciences Research Council (EPSRC), is being led by researchers at the University of St Andrews with partners at Strathclyde and Newcastle.

The new design has the potential to improve the performance of portable electronic products and give a major boost to the renewable energy industry. The batteries will enable a constant electrical output from sources such as wind or solar, which stop generating when the weather changes or night falls.

Improved capacity is thanks to the addition of a component that uses oxygen drawn from the air during discharge, replacing one chemical constituent used in rechargeable batteries today. Not having to carry the chemicals around in the battery offers more energy for the same size battery. Reducing the size and weight of batteries with the necessary charge capacity has been a long-running battle for developers of electric cars.

The STAIR (St Andrews Air) cell should be cheaper than today’s rechargeables, too. The new component is made of porous carbon, which is far less expensive than the lithium cobalt oxide it replaces.

This four-year research project, which reaches its halfway mark in July, builds on the discovery at the university that the carbon component’s interaction with air can be repeated, creating a cycle of charge and discharge. Subsequent work has more than tripled the capacity to store charge in the STAIR cell.

Principal investigator on the project, Professor Peter Bruce of the Chemistry Department at the University of St Andrews, says: “Our target is to get a five to ten fold increase in storage capacity, which is beyond the horizon of current lithium batteries. Our results so far are very encouraging and have far exceeded our expectations.”

“The key is to use oxygen in the air as a re-agent, rather than carry the necessary chemicals around inside the battery,” says Bruce.

The oxygen, which will be drawn in through a surface of the battery exposed to air, reacts within the pores of the carbon to discharge the battery. “Not only is this part of the process free, the carbon component is much cheaper than current technology,” says Bruce. He estimates that it will be at least five years before the STAIR cell is commercially available.

The project is focused on understanding more about how the chemical reaction of the battery works and investigating how to improve it. The research team is also working towards making a STAIR cell prototype suited, in the first instance, for small applications, such as mobile phones or MP3 players.

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