New Way to Harvest Energy from Sunlight

New Way to Harvest Energy from Sunlight

  9:37:00 AM    Science Lover

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Professor Richard Watt and his chemistry students suspected that a common protein could potentially react with sunlight and harvest its energy -- similar to what chlorophyll does during photosynthesis.

BYU chemistry professor Richard Watt. (Credit: Image courtesy of Brigham Young University)

The story of how they proved it sounds as colorful as the legend of the leprechaun who hid his pot of gold at the end of the rainbow.

They started with citric acid from oranges and mixed it with the protein. Next they dissolved gold powder into the solution. Then they put vials of the yellow-colored mixture in direct sunlight and crossed their fingers in the hope that it would turn purple.

Here's the reason why: If it turned purple, that would signal that the gold atoms had received electrons and used the donated energy to bunch together as small, purple-colored nanoparticles. And that would mean that the protein used the sunlight to excite the citric acid and trigger a transfer of energy.

While direct sunlight did the trick in about 20 minutes, a high-powered tungsten mercury lamp worked much faster.

"We set the system up, turned on the light, and the solution turned purple," Watt said. "We knew that we'd proved the concept."

The beauty of this experiment lies not in its colors -- unless, of course, you're thinking of it as a potential "green" energy source that keeps the environment clean.

The BYU researchers published their experiments in the Journal of Nanoparticle Research. The final step of this project will involve connecting the protein to an electrode to channel the energy into a battery or fuel cell. The BYU chemists will partner with Jae-Woo Kim of the National Institute of Aerospace for this next stage of the work.

Professor Watt's pedigree includes a post-doc at Princeton, a father who developed a fuel cell that runs on sugar and weed-killer and a more distant ancestor credited with inventing the first practical steam engine. That ancestor is also the Scottish engineer for whom the unit of power "watt" is named.

Co-authors on the new study include BYU graduate Jeremiah Keyes, grad student Robert Hilton and Jeff Farrer, who runs an electron microscope lab at BYU.

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Dry Water Could Make a Big Splash Commercially, Help Fight Global Warming

Dry Water Could Make a Big Splash Commercially, Help Fight Global Warming

  12:40:00 AM    Science Lover

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An unusual substance known as "dry water," which resembles powdered sugar, could provide a new way to absorb and store carbon dioxide, the major greenhouse gas that contributes to global warming, scientists reported at the 240th National Meeting of the American Chemical Society.

Powdered material called "dry water" could provide a new way to store carbon dioxide in an effort to fight global warming. (Credit: Ben Carter)

The powder shows bright promise for a number of other uses, they said. It may, for instance, be a greener, more energy-efficient way of jumpstarting the chemical reactions used to make hundreds of consumer products. Dry water also could provide a safer way to store and transport potentially harmful industrial materials.

"There's nothing else quite like it," said Ben Carter, Ph.D., researcher for study leader Professor Andrew Cooper. "Hopefully, we may see 'dry water' making waves in the future."

Carter explained that the substance became known as "dry water" because it consists of 95 percent water and yet is a dry powder. Each powder particle contains a water droplet surrounded by modified silica, the stuff that makes up ordinary beach sand. The silica coating prevents the water droplets from combining and turning back into a liquid. The result is a fine powder that can slurp up gases, which chemically combine with the water molecules to form what chemists term a hydrate.

Dry water was discovered in 1968 and got attention for its potential use in cosmetics. Scientists at the University of Hull, U.K. rediscovered it in 2006 in order to study its structure, and Cooper's group at the University of Liverpool has since expanded its range of potential applications.

One of the most recent involves using dry water as a storage material for gases, including carbon dioxide. In laboratory-scale research, Cooper and co-workers found that dry water absorbed over three times as much carbon dioxide as ordinary, uncombined water and silica in the same space of time. This ability to absorb large amounts of carbon dioxide gas as a hydrate could make it useful in helping to reduce global warming, the scientists suggested.

Cooper and colleagues demonstrated in previous studies that dry water is also useful for storing methane, a component of natural gas, and may help expand its use as a future energy source. In particular, they hope that engineers can use the powder to collect and transport stranded deposits of natural gas. This also exists on the ocean floor in the form of gas hydrates, a form of frozen methane also known as the "ice that burns." The powder could also provide a safer, more convenient way to store methane fuel for use in vehicles powered by natural gas. "A great deal of work remains to be done before we could reach that stage," Carter added.

In another potential new application, the scientists also showed that dry water is a promising means to speed up catalyzed reactions between hydrogen gas and maleic acid to produce succinic acid, a feedstock or raw material widely used to make drugs, food ingredients, and other consumer products. Manufacturers usually have to stir these substances together to get them to react. By developing dry water particles that contain maleic acid, Cooper and colleagues showed that they could speed up the acid's reaction with hydrogen without any stirring, resulting in a greener, more energy-efficient process.

"If you can remove the need to stir your reactions, then potentially you're making considerable energy savings," Carter said.

Prof. Cooper's team describes an additional new application in which dry water technology shows promise for storing liquids, particularly emulsions. Emulsions are mixtures of two or more unblendable liquids, such as the oil and water mixture in mayonnaise. The scientists showed that they could transform a simple emulsion into a dry powder that is similar to dry water. The resulting powder could make it safer and easier for manufacturers to store and transport potentially harmful liquids.

Carter noted that he and his colleagues are seeking commercial or academic collaboration to further develop the dry water technology. The U.K. Engineering and Physical Sciences Research Council (EPSRC) and the Center for Materials Discovery provided funding and technical support for this study.

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'Nature's Batteries' Powered Early Lifeforms?

'Nature's Batteries' Powered Early Lifeforms?

  8:37:00 PM    Science Lover

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Researchers at the University of Leeds have uncovered new clues to the origins of life on Earth.

The team found that a compound known as pyrophosphite may have been an important energy source for primitive lifeforms.

There are several conflicting theories of how life on Earth emerged from inanimate matter billions of years ago -- a process known as abiogenesis.

"It's a chicken and egg question," said Dr Terry Kee of the University of Leeds, who led the research. "Scientists are in disagreement over what came first -- replication, or metabolism. But there is a third part to the equation -- and that is energy."

A space-filling molecular model of ATP (adenosine 
triphosphate), with hydrogen shown white, oxygen 
red, phosphorous orange, nitrogen turquoise, and 
carbon black, and with ions marked by a negative 
sign. (Credit: Courtesy of Wikipedia)

All living things require a continual supply of energy in order to function. This energy is carried around our bodies within certain molecules, one of the best known being ATP (adenosine triphosphate), which converts heat from the sun into a useable form for animals and plants.

At any one time, the human body contains just 250g of ATP -- this provides roughly the same amount of energy as a single AA battery. This ATP store is being constantly used and regenerated in cells via a process known as respiration, which is driven by natural catalysts called enzymes.

"You need enzymes to make ATP and you need ATP to make enzymes," explained Dr Kee. "The question is: where did energy come from before either of these two things existed? We think that the answer may lie in simple molecules such as pyrophosphite which is chemically very similar to ATP, but has the potential to transfer energy without enzymes."

The key to the battery-like properties of both ATP and pyrophosphite is an element called phosphorus, which is essential for all living things. Not only is phosphorus the active component of ATP, it also forms the backbone of DNA and is important in the structure of cell walls.

But despite its importance to life, it is not fully understood how phosphorus first appeared in our atmosphere. One theory is that it was contained within the many meteorites that collided with the Earth billions of years ago.

"Phosphorus is present within several meteoritic minerals and it is possible that this reacted to form pyrophosphite under the acidic, volcanic conditions of early Earth," added Dr Kee.

The findings, published in the journal Chemical Communications, are the first to suggest that pyrophosphite may have been relevant in the shift from basic chemistry to complex biology when life on earth began. Since completing this research, Dr Kee and his team have found even further evidence for the importance of this molecule and now hope to team up with collaborators from NASA to investigate its role in abiogenesis.

The study was funded by the STFC and the Engineering and Physical Sciences Research Council (EPSRC).

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'Cold Fusion' Moves Closer to Mainstream Acceptance

'Cold Fusion' Moves Closer to Mainstream Acceptance

  11:36:00 PM    Science Lover

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A potential new energy source so controversial that people once regarded it as junk science is moving closer to acceptance by the mainstream scientific community. That's the conclusion of the organizer of one of the largest scientific sessions on the topic -- "cold fusion" -- being held here for the next two days in the Moscone Center during the 239th National Meeting of the American Chemical Society (ACS).

A new "calorimeter," shown immersed in this water bath, provides the first inexpensive means of identifying the hallmark of cold fusion reactions: the production of excess heat. (Credit: Melvin Miles)

 

"Years ago, many scientists were afraid to speak about 'cold fusion' to a mainstream audience," said Jan Marwan, Ph.D., the internationally known expert who organized the symposium. Marwan heads the research firm, Dr. Marwan Chemie in Berlin, Germany. Entitled "New Energy Technology," the symposium will include nearly 50 presentations describing the latest discoveries on the topic.

The presentations describe invention of an inexpensive new measuring device that could enable more labs to begin cold fusion research; indications that cold fusion may occur naturally in certain bacteria; progress toward a battery based on cold fusion; and a range of other topics. Marwan noted that many of the presentations suggest that cold fusion is real, with a potential to contribute to energy supplies in the 21st Century.

"Now most of the scientists are no longer afraid and most of the cold fusion researchers are attracted to the ACS meeting," Marwan said. "I've also noticed that the field is gaining new researchers from universities that had previously not pursued cold fusion research. More and more people are becoming interested in it. There's still some resistance to this field. But we just have to keep on as we have done so far, exploring cold fusion step by step, and that will make it a successful alternative energy source. With time and patience, I'm really optimistic we can do this!"

The term "cold fusion" originated in 1989 when Martin Fleishmann and Stanley Pons claimed achieving nuclear fusion at room temperature with a simple, inexpensive tabletop device. That claim fomented an international sensation because nuclear fusion holds potential for providing the world with a virtually limitless new source of energy. Fuel for fusion comes from ordinary seawater, and estimates indicate that 1 gallon of seawater packs the energy equivalent of 16 gallons of gasoline at 100 percent efficiency for energy production. The claim also ignited scepticism, because conventional wisdom said that achieving fusion required multi-billion-dollar fusion reactors that operate at tens of millions of degrees Fahrenheit.

When other scientists could not reproduce the Pons-Fleishmann results, research on cold fusion fell into disrepute. Humiliated by the scientific establishment, their reputations ruined, Pons and Fleishmann closed their labs, fled the country, and dropped out of sight. The handful of scientists who continued research avoided the term "cold fusion." Instead, they used the term "low energy nuclear reactions (LENR)." Research papers at the ACS symposium openly refer to "cold fusion" and some describe cold fusion as the "Fleishmann-Pons Effect" in honor of the pioneers, Marwan noted.

"The field is now experiencing a rebirth in research efforts and interest, with evidence suggesting that cold fusion may be a reality." Marwan said. He noted, for instance, that the number of presentations on the topic at ACS National Meetings has quadrupled since 2007.

Among the reports scheduled for the symposium are:

• Michael McKubre, Ph.D., of SRI International in Menlo Park, Calif., provides an overview of cold fusion research. McKubre will discuss current knowledge in the field and explain why some doubts exist in the broader scientific community. He will also discuss recent experimental work performed at SRI. McKubre will focus on fusion, heat production and nuclear products. [3pm, Monday March 22, Cyril Magnin ]

• George Miley, Ph.D., reports on progress toward a new type of battery that works through a new cold fusion process and has a longer life than conventional batteries. The battery consists of a special type of electrolytic cell that operates at low temperature. The process involves purposely creating defects in the metal electrode of the cell. Miley is a professor at the University of Illinois in Urbana and director of its Fusion Studies Lab. [11am, Sunday March 21, Cyril Magnin I]

• Melvin Miles, Ph.D., describes development of the first inexpensive instrument for reliably identifying the hallmark of cold fusion reactions: Production of excess heat from tabletop fusion devices now in use. Current "calorimeters," devices that measure excess heat, tend to be too complicated and inefficient for reliable use. The new calorimeter could boost the quality of research and open the field to scores of new scientists in university, government, and private labs, Miles suggests. He is with Dixie State College in St. George, Utah. [2.30pm, Sunday March 21, Cyril Magnin I]

• Vladimir Vysotskii, Ph.D., presents surprising experimental evidence that bacteria can undergo a type of cold fusion process and could be used to dispose of nuclear waste. He will describe studies of nuclear transmutation -- the transformation of one element into another -- of stable and radioactive isotopes in biological systems. Vysotskii is a scientist with Kiev National Shevchenko University in Kiev, Ukraine. [11.20am, Monday March 22, Cyril Magnin I].

• Tadahiko Mizuno, Ph.D., discusses an unconventional cold fusion device that uses phenanthrene, a substance found in coal and oil, as a reactant. He reports on excess heat production and gamma radiation production from the device. "Overall heat production exceeded any conceivable chemical reaction by two orders of magnitude," Mizuno noted. He is with Hokkaido University in Japan, and wrote the book Nuclear Transmutation: The Reality of Cold Fusion. [3pm, Sunday March 21, Cyril Magnin I]

• Peter Hagelstein, Ph.D., describes new theoretical models to help explain excess heat production in cold fusion, one of the most controversial aspects of the field. He notes that in a nuclear reaction, one would expect that the energy produced would appear as kinetic energy in the products, but in the Fleischmann-Pons experiment there do not appear energetic particles in amounts consistent with the energy observed. His simple models help explain the observed energy changes, including the type and quantity of energy produced. Hagelstein is with the Massachusetts Institute of Technology. [10.20am, Sunday March 21, Cyril Magnin I].

• Xing Zhong Li, Ph.D., presents research demonstrating that cold fusion can occur without the production of strong nuclear radiation. He is developing a cold fusion reactor that demonstrates this principle. Li is a scientist with Tsinghua University in Beijing, China. [9.10am, Sunday March 21, Cyril Magnin I].

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Scientists Create a Solar Energy Device from a Plant Protein Structure

Scientists Create a Solar Energy Device from a Plant Protein Structure

  9:46:00 PM    Science Lover

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If harnessing the unlimited solar power of the sun were easy, we wouldn't still have the greenhouse gas problem that results from the use of fossil fuel. And while solar energy systems work moderately well in hot desert climates, they are still inefficient and contribute only a small percentage of the general energy demand. A new solution may be coming from an unexpected source -- a source that may be on your dinner plate tonight.

New research suggests that minute crystals from peas can be illuminated and used as small battery chargers or form the core of more efficient artificial solar cells. (Credit: iStockphoto/Andrea Skjold)

"Looking at the most complicated membrane structure found in a plant, we deciphered a complex membrane protein structure which is the core of our new proposed model for developing 'green' energy," says structural biologist Prof. Nathan Nelson of Tel Aviv University's Department of Biochemistry. Isolating the minute crystals of the PSI super complex from the pea plant, Prof. Nelson suggests these crystals can be illuminated and used as small battery chargers or form the core of more efficient artificial solar cells.

Nanoscience is the science of small particles of materials and is one of the most important research frontiers in modern technology. In nature, positioning of molecules with sub-nanometer precision is routine, and crucial to the operation of biological complexes such as photosynthetic complexes. Prof. Nelson's research concentrates on this aspect.

The mighty PSI

To generate useful energy, plants have evolved very sophisticated "nano-machinery" which operates with light as its energy source and gives a perfect quantum yield of 100%. Called the Photosystem I (PSI) complex, this complex was isolated from pea leaves, crystalized and its crystal structure determined by Prof. Nelson to high resolution, which enabled him to describe in detail its intricate structure.

"My research aims to come close to achieving the energy production that plants can obtain when converting sun to sugars in their green leaves," explains Prof. Nelson.

Described in 1905 by Albert Einstein, quantum physics and photons explained the basic principles of how light energy works. Once light is absorbed in plant leaves, it energizes an electron which is subsequently used to support a biochemical reaction, like sugar production.

"If we could come even close to how plants are manufacturing their sugar energy, we'd have a breakthrough. It's therefore important to solve the structure of this nano-machine to understand its function," says Prof. Nelson, whose lab is laying the foundations for this possibility.

Since the PSI reaction center is a pigment-protein complex responsible for the photosynthetic conversion of light energy to another form of energy like chemical energy, these reaction centers, thousands of which are precisely packed in the crystals, may be used to convert light energy to electricity and serve as electronic components in a variety of different devices.

"One can imagine our amazement and joy when, upon illumination of those crystals placed on gold covered plates, we were able to generate a voltage of 10 volts. This won't solve our world's energy problem, but this could be assembled in power switches for low-power solar needs, for example," he concludes.

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'Cold Fusion' Rebirth? New Evidence For Existence Of Controversial Energy Source

'Cold Fusion' Rebirth? New Evidence For Existence Of Controversial Energy Source

  2:40:00 AM    Science Lover

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ScienceDaily (2009-03-23) -- Researchers are reporting compelling new scientific evidence for the existence of low-energy nuclear reactions, the process once called "cold fusion" that may promise a new source of energy. Scientists describe what they term the first clear visual evidence that LENR devices can produce neutrons, which scientists view as tell-tale signs of nuclear fusion reactions.

Source : ScienceDaily
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