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Showing posts with label Periodic table. Show all posts
Showing posts with label Periodic table. Show all posts

Sunday, November 13, 2011

A revolution in knot theory


In the 19th century, Lord Kelvin made the inspired guess that elements are knots in the "ether". Hydrogen would be one kind of knot, oxygen a different kind of knot---and so forth throughout the periodic table of elements. This idea led Peter Guthrie Tait to prepare meticulous and quite beautiful tables of knots, in an effort to elucidate when two knots are truly different. From the point of view of physics, Kelvin and Tait were on the wrong track: the atomic viewpoint soon made the theory of ether obsolete. But from the mathematical viewpoint, a gold mine had been discovered: The branch of mathematics now known as "knot theory" has been burgeoning ever since.
This knot has Gauss code O1U2O3U1O2U3.
Credit: Graphic by Sam Nelson.

In his article "The Combinatorial Revolution in Knot Theory", to appear in the December 2011 issue of the Notices of the AMS, Sam Nelson describes a novel approach to knot theory that has gained currency in the past several years and the mysterious new knot-like objects discovered in the process.

As sailors have long known, many different kinds of knots are possible; in fact, the variety is infinite. A *mathematical* knot can be imagined as a knotted circle: Think of a pretzel, which is a knotted circle of dough, or a rubber band, which is the "un-knot" because it is not knotted. Mathematicians study the patterns, symmetries, and asymmetries in knots and develop methods for distinguishing when two knots are truly different.

Mathematically, one thinks of the string out of which a knot is formed as being a one-dimensional object, and the knot itself lives in three-dimensional space. Drawings of knots, like the ones done by Tait, are projections of the knot onto a two-dimensional plane. In such drawings, it is customary to draw over-and-under crossings of the string as broken and unbroken lines. If three or more strands of the knot are on top of each other at single point, we can move the strands slightly without changing the knot so that every point on the plane sits below at most two strands of the knot. A planar knot diagram is a picture of a knot, drawn in a two-dimensional plane, in which every point of the diagram represents at most two points in the knot. Planar knot diagrams have long been used in mathematics as a way to represent and study knots.

As Nelson reports in his article, mathematicians have devised various ways to represent the information contained in knot diagrams. One example is the Gauss code, which is a sequence of letters and numbers wherein each crossing in the knot is assigned a number and the letter O or U, depending on whether the crossing goes over or under. The Gauss code for a simple knot might look like this: O1U2O3U1O2U3.

In the mid-1990s, mathematicians discovered something strange. There are Gauss codes for which it is impossible to draw planar knot diagrams but which nevertheless behave like knots in certain ways. In particular, those codes, which Nelson calls *nonplanar Gauss codes*, work perfectly well in certain formulas that are used to investigate properties of knots. Nelson writes: "A planar Gauss code always describes a [knot] in three-space; what kind of thing could a nonplanar Gauss code be describing?" As it turns out, there are "virtual knots" that have legitimate Gauss codes but do not correspond to knots in three-dimensional space. These virtual knots can be investigated by applying combinatorial techniques to knot diagrams.

Just as new horizons opened when people dared to consider what would happen if -1 had a square root---and thereby discovered complex numbers, which have since been thoroughly explored by mathematicians and have become ubiquitous in physics and engineering---mathematicians are finding that the equations they used to investigate regular knots give rise to a whole universe of "generalized knots" that have their own peculiar qualities. Although they seem esoteric at first, these generalized knots turn out to have interpretations as familiar objects in mathematics. "Moreover," Nelson writes, "classical knot theory emerges as a special case of the new generalized knot theory."

More information: Related to this subject are an upcoming issue of the Journal of Knot Theory and its Ramifications, devoted to virtual knot theory, and the upcoming Knots in Washington conference at George Washington University, December 2-4, 2011, which will focus on on "Categorification of Knots, Algebras, and Quandles; Quantum Computing".

Provided by American Mathematical Society

Friday, June 10, 2011

Superatoms With Magnetic Shells Discovered



A team of Virginia Commonwealth University scientists has discovered a new class of 'superatoms' -- a stable cluster of atoms that can mimic different elements of the periodic table -- with unusual magnetic characteristics.
A proposed assembly of FeMg8 magnetic superatoms 
where the directions of magnetic moment is indicated 
by arrows. (Credit: Image courtesy of Victor Medel/VCU)

The superatom contains magnetized magnesium atoms, an element traditionally considered as non-magnetic. The metallic character of magnesium along with infused magnetism may one day be used to create molecular electronic devices for the next generation of faster processors, larger memory storage and quantum computers.

In a study published online in the Early Edition of the Proceedings of the National Academy of Sciences, the team reports that the newly discovered cluster consisting of one iron and eight magnesium atoms acts like a tiny magnet that derives its magnetic strength from the iron and magnesium atoms. The combined unit matches the magnetic strength of a single iron atom while preferentially allowing electrons of specific spin orientation to be distributed throughout the cluster.

Through an elaborate series of theoretical studies, Shiv N. Khanna, Ph.D., a Commonwealth professor in the VCU Department of Physics, and his team examined the electronic and magnetic properties of clusters having one iron atom surrounded by multiple magnesium atoms. The team included instructor J. Ulises Reveles and Victor M. Medel, a post-doctoral associate, both from VCU; A. W. Castleman Jr., Ph.D., the Evan Pugh Professor of Chemistry and Physics, and Eberly Distinguished chair in Science in the Department of Chemistry at Penn State University; and Prasenjit Sen and Vikas Chauhan from the Harish-Chandra Research Institute in Allahabad, India.

"Our research opens a new way of infusing magnetic character in otherwise non-magnetic elements through controlled association with a single magnetic atom. An important objective was to discover what combination of atoms would lead to a species that is stable as we put multiple units together," said Khanna.

"The combination of magnetic and conducting attributes was also desirable. Magnesium is a good conductor of electricity and, hence, the superatom combines the benefit of magnetic character along with ease of conduction through its outer skin," he said.

The team found that when the cluster had eight magnesium atoms it acquired extra stability due to filled electronic shells that were far separated from the unfilled shells. An atom is in a stable configuration when its outermost shell is full and far separated from unfilled shells, as found in inert gas atoms. Khanna said that such phenomena commonly occur with paired electrons which are non-magnetic, but in this study the magnetic electronic shell showed stability.

According to Khanna, the new cluster had a magnetic moment of four Bohr magnetons, which is almost twice that of an iron atom in solid iron magnets. A magnetic moment is a measure of the magnetic strength of the cluster. Although the periodic table has more than one hundred elements, there are only nine elements that exhibit magnetic character in solid form.

"A combination such as the one we have created here can lead to significant developments in the area of "molecular electronics" where such devices allow the flow of electrons with particular spin orientation desired for applications such as quantum computers. These molecular devices are also expected to help make denser integrated devices, higher data processing, and other benefits," said Reveles.

Khanna and his team are conducting preliminary studies on the assemblies of the new superatoms and have made some promising observations that may have applications in spintronics. Spintronics is a process using electron spin to synthesize new devices for memory and data processing.

This research was supported by the U.S. Department of Energy.