Novel Nanowires Boost Fuel Cell Efficiency

Novel Nanowires Boost Fuel Cell Efficiency

  12:26:00 AM    Science Lover

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Fuel cells have been touted as a cleaner solution to tomorrow's energy needs, with potential applications in everything from cars to computers.

Taylor and Schroers engineered nanowires out of a novel material called bulk metallic glass in order to make fuel cell catalyst systems more durable and efficient. (Credit: Golden Kumar and Miriam Schroers)

But one reason fuel cells aren't already more widespread is their lack of endurance. Over time, the catalysts used even in today's state-of-the-art fuels cells break down, inhibiting the chemical reaction that converts fuel into electricity. In addition, current technology relies on small particles coated with the catalyst; however, the particles' limited surface area means only a fraction of the catalyst is available at any given time.

Now a team of engineers at the Yale School of Engineering & Applied Science has created a new fuel cell catalyst system using nanowires made of a novel material that boosts long-term performance by 2.4 times compared to today's technology. Their findings appear on the cover of the April issue of ACS Nano.

Yale engineers Jan Schroers and André Taylor have developed miniscule nanowires made of an innovative metal alloy known as a bulk metallic glass (BMG) that have high surface areas, thereby exposing more of the catalyst. They also maintain their activity longer than traditional fuel cell catalyst systems.

Current fuel cell technology uses carbon black, an inexpensive and electrically conductive carbon material, as a support for platinum particles. The carbon transports electricity, while the platinum is the catalyst that drives the production of electricity. The more platinum particles the fuel is exposed to, the more electricity is produced. Yet carbon black is porous, so the platinum inside the inner pores may not be exposed. Carbon black also tends to corrode over time.

"In order to produce more efficient fuel cells, you want to increase the active surface area of the catalyst, and you want your catalyst to last," Taylor said.

At 13 nanometers in scale (about 1/10,000 the width of a human hair), the BMG nanowires that Schroers and Taylor developed are about three times smaller than carbon black particles. The nanowires' long, thin shape gives them much more active surface area per mass compared to carbon black. In addition, rather than sticking platinum particles onto a support material, the Yale team incorporated the platinum into the nanowire alloy itself, ensuring that it continues to react with the fuel over time.

It's the nanowires' unique chemical composition that makes it possible to shape them into such small rods using a hot-press method, said Schroers, who has developed other BMG alloys that can also be blow molded into complicated shapes. The BMG nanowires also conduct electricity better than carbon black and carbon nanotubes, and are less expensive to process.

So far Taylor has tested their catalyst system for alcohol-based fuel cells (including those that use ethanol and methanol as fuel sources), but they say the system could be used in other types of fuel cells and could one day be used in portable electronic devices such as laptop computers and cell phones as well as in remote sensors.

"This is the introduction of a new class of materials that can be used as electrocatalysts," Taylor said. "It's a real step toward making fuel cells commercially viable and, ultimately, supplementing or replacing batteries in electronic devices."

Other authors of the paper include Marcelo Carmo, Ryan C. Sekol, Shiyan Ding and Golden Kumar (all of Yale University).

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Replace Silicon With Graphene on Nanocircuitry

Replace Silicon With Graphene on Nanocircuitry

  7:57:00 PM    Science Lover

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Scientists have made a breakthrough toward creating nanocircuitry on graphene, widely regarded as the most promising candidate to replace silicon as the building block of transistors. They have devised a simple and quick one-step process based on thermochemical nanolithography (TCNL) for creating nanowires, tuning the electronic properties of reduced graphene oxide on the nanoscale and thereby allowing it to switch from being an insulating material to a conducting material.

In a technique known as thermochemical 
nanolithography, the tip of an atomic force microscope 
uses heat to turn graphene oxide into reduced 
graphene oxide, a substance that can be used to produce 
nanocircuits and nanowires with controllable conductivity. 
(Credit: University of Illinois at Urbana-Champaign)

The technique works with multiple forms of graphene and is poised to become an important finding for the development of graphene electronics. The research appears in the June 11, 2010, issue of the journal Science.

Scientists who work with nanocircuits are enthusiastic about graphene because electrons meet with less resistance when they travel along graphene compared to silicon and because today's silicon transistors are nearly as small as allowed by the laws of physics. Graphene also has the edge due to its thickness -- it's a carbon sheet that is a single atom thick. While graphene nanoelectronics could be faster and consume less power than silicon, no one knew how to produce graphene nanostructures on such a reproducible or scalable method. That is until now.

"We've shown that by locally heating insulating graphene oxide, both the flakes and epitaxial varieties, with an atomic force microscope tip, we can write nanowires with dimensions down to 12 nanometers. And we can tune their electronic properties to be up to four orders of magnitude more conductive. We've seen no sign of tip wear or sample tearing," said Elisa Riedo, associate professor in the School of Physics at the Georgia Institute of Technology.

On the macroscale, the conductivity of graphene oxide can be changed from an insulating material to a more conductive graphene-like material using large furnaces.

Now, the research team used TCNL to increase the temperature of reduced graphene oxide at the nanoscale, so they can draw graphene-like nanocircuits. They found that when it reached 130 degrees Celsius, the reduced graphene oxide began to become more conductive.

"So the beauty of this is that we've devised a simple, robust and reproducible technique that enables us to change an insulating sample into a conducting nanowire. These properties are the hallmark of a productive technology," said Paul Sheehan, head of the Surface Nanoscience and Sensor Technology Section at the Naval Research Laboratory in Washington, D.C.

The research team tested two types of graphene oxide -- one made from silicon carbide, the other with graphite powder.

"I think there are three things about this study that make it stand out," said William P. King, associate professor in the Mechanical Science and Engineering department at the University of Illinois at Urbana-Champaign. "First, is that the entire process happens in one step. You go from insulating graphene oxide to a functional electronic material by simply applying a nano-heater. Second, we think that any type of graphene will behave this way. Third, the writing is an extremely fast technique. These nanostructures can be synthesized at such a high rate that the approach could be very useful for engineers who want to make nanocircuits."

"This project is an excellent example of the new technologies that epitaxial graphene electronics enables," said Walt de Heer, Regent's Professor in Georgia Tech's School of Physics and the original proponent of epitaxial graphene in electronics. His study led to the establishment of the Materials Research Science and Engineering Center two years ago. "The simple conversion from graphene oxide to graphene is an important and fast method to produce conducting wires. This method can be used not only for flexible electronics, but it is possible, sometime in the future, that the bio-compatible graphene wires can be used to measure electrical signals from single biological cells."

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