Novel Device Removes Heavy Metals from Water

Novel Device Removes Heavy Metals from Water

  9:33:00 AM    Science Lover

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Engineers at Brown University have developed a system that cleanly and efficiently removes trace heavy metals from water. In experiments, the researchers showed the system reduced cadmium, copper, and nickel concentrations, returning contaminated water to near or below federally acceptable standards. The technique is scalable and has viable commercial applications, especially in the environmental remediation and metal recovery fields.

Heavy metal removal Brown engineers have devised an
automated system that combines chemical precipitation
with electrolytic techniques in a cyclic fashion to remove
mixtures of trace heavy metals from contaminated water.
(Credit: Calo Lab/Brown University)

Results appear in the Chemical Engineering Journal.

An unfortunate consequence of many industrial and manufacturing practices, from textile factories to metalworking operations, is the release of heavy metals in waterways. Those metals can remain for decades, even centuries, in low but still dangerous concentrations.

Ridding water of trace metals "is really hard to do," said Joseph Calo, professor emeritus of engineering who maintains an active laboratory at Brown. He noted the cost, inefficiency, and time needed for such efforts. "It's like trying to put the genie back in the bottle."

That may be changing. Calo and other engineers at Brown describe a novel method that collates trace heavy metals in water by increasing their concentration so that a proven metal-removal technique can take over. In a series of experiments, the engineers report the method, called the cyclic electrowinning/precipitation (CEP) system, removes up to 99 percent of copper, cadmium, and nickel, returning the contaminated water to federally accepted standards of cleanliness. The automated CEP system is scalable as well, Calo said, so it has viable commercial potential, especially in the environmental remediation and metal recovery fields. The system's mechanics and results are described in a paper published in the Chemical Engineering Journal.

A proven technique for removing heavy metals from water is through the reduction of heavy metal ions from an electrolyte. While the technique has various names, such as electrowinning, electrolytic removal/recovery or electroextraction, it all works the same way, by using an electrical current to transform positively charged metal ions (cations) into a stable, solid state where they can be easily separated from the water and removed. The main drawback to this technique is that there must be a high-enough concentration of metal cations in the water for it to be effective; if the cation concentration is too low -- roughly less than 100 parts per million -- the current efficiency becomes too low and the current acts on more than the heavy metal ions.

Another way to remove metals is through simple chemistry. The technique involves using hydroxides and sulfides to precipitate the metal ions from the water, so they form solids. The solids, however, constitute a toxic sludge, and there is no good way to deal with it. Landfills generally won't take it, and letting it sit in settling ponds is toxic and environmentally unsound. "Nobody wants it, because it's a huge liability," Calo said.

The dilemma, then, is how to remove the metals efficiently without creating an unhealthy byproduct. Calo and his co-authors, postdoctoral researcher Pengpeng Grimshaw and George Hradil, who earned his doctorate at Brown and is now an adjunct professor, combined the two techniques to form a closed-loop system. "We said, 'Let's use the attractive features of both methods by combining them in a cyclic process,'" Calo said.

It took a few years to build and develop the system. In the paper, the authors describe how it works. The CEP system involves two main units, one to concentrate the cations and another to turn them into stable, solid-state metals and remove them. In the first stage, the metal-laden water is fed into a tank in which an acid (sulfuric acid) or base (sodium hydroxide) is added to change the water's pH, effectively separating the water molecules from the metal precipitate, which settles at the bottom. The "clear" water is siphoned off, and more contaminated water is brought in. The pH swing is applied again, first redissolving the precipitate and then reprecipitating all the metal, increasing the metal concentration each time. This process is repeated until the concentration of the metal cations in the solution has reached a point at which electrowinning can be efficiently employed.

When that point is reached, the solution is sent to a second device, called a spouted particulate electrode (SPE). This is where the electrowinning takes place, and the metal cations are chemically changed to stable metal solids so they can be easily removed. The engineers used an SPE developed by Hradil, a senior research engineer at Technic Inc., located in Cranston, R.I. The cleaner water is returned to the precipitation tank, where metal ions can be precipitated once again. Further cleaned, the supernatant water is sent to another reservoir, where additional processes may be employed to further lower the metal ion concentration levels. These processes can be repeated in an automated, cyclic fashion as many times as necessary to achieve the desired performance, such as to federal drinking water standards.

In experiments, the engineers tested the CEP system with cadmium, copper, and nickel, individually and with water containing all three metals. The results showed cadmium, copper, and nickel were lowered to 1.50, 0.23 and 0.37 parts per million (ppm), respectively -- near or below maximum contaminant levels established by the Environmental Protection Agency. The sludge is continuously formed and redissolved within the system so that none is left as an environmental contaminant.

"This approach produces very large volume reductions from the original contaminated water by electrochemical reduction of the ions to zero-valent metal on the surfaces of the cathodic particles," the authors write. "For an initial 10 ppm ion concentration of the metals considered, the volume reduction is on the order of 106."

Calo said the approach can be used for other heavy metals, such as lead, mercury, and tin. The researchers are currently testing the system with samples contaminated with heavy metals and other substances, such as sediment, to confirm its operation.

The research was funded by the National Institute of Environmental Health Sciences, a branch of the National Institutes of Health, through the Brown University Superfund Research Program.

Editors: Brown University has a fiber link television studio available for domestic and international live and taped interviews, and maintains an ISDN line for radio interviews. For more information, call (401) 863-2476.

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Leaping Lizards and Dinosaurs Inspire Robot Design

Leaping Lizards and Dinosaurs Inspire Robot Design

  10:48:00 PM    Science Lover

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Leaping lizards have a message for robots: Get a tail! University of California, Berkeley, biologists and engineers -- including undergraduate and graduate students -- studied how lizards manage to leap successfully even when they slip and stumble. They found that lizards swing their tails upward to prevent them from pitching head-over-heels into a rock.

An Agama lizard next to Tailbot, a toy car with an attached tail 
and a toy figure. Sensors detect Tailbot's orientation and swing 
the tail upward to keep the robot from pitching forward, similar 
to the way the lizard uses its tail. 
(Credit: Photo by Robert Full lab, UC Berkeley.)

But after the team added a tail to a robotic car named Tailbot, they discovered that counteracting the effect of a slip is not as simple as throwing your tail in the air. Instead, robots and lizards must actively adjust the angle of their tails just right to remain upright.

"We showed for the first time that lizards swing their tail up or down to counteract the rotation of their body, keeping them stable," said team leader Robert J. Full, UC Berkeley professor of integrative biology. "Inspiration from lizard tails will likely lead to far more agile search-and-rescue robots, as well as ones having greater capability to more rapidly detect chemical, biological or nuclear hazards."

Agile therapod dinosaurs like the velociraptor depicted in the movie Jurassic Park may also have used their tails as stabilizers to prevent forward pitch, Full said. Their tail movement is illustrated in a prescient chase sequence from the 1993 movie in which the animated animal leaps from a balcony onto a T. rex skeleton.

"Muscles willing, the dinosaur could be even more effective with a swing of its tail in controlling body attitude than the lizards," Full said.

Student involvement crucial to research

Full and his laboratory colleagues, including both engineering and biology students, will report their discoveries online on Jan. 5 in advance of publication in the Jan. 12 print edition of the journal Nature. The paper's first author, mechanical engineering graduate student Thomas Libby, also will report the results on Jan. 7 at the annual meeting of the Society for Integrative and Comparative Biology in Charleston, S.C.

Full is enthusiastic about the interplay fostered at UC Berkeley between biologists and engineers in the Center for Interdisciplinary Bio-inspiration in Education and Research (CiBER) lab, within which he offers a research-based teaching lab that provides dozens of undergraduate students with an opportunity to conduct cutting-edge research in teams with graduate students. Each team experiences the benefits of how biologists and engineers approach a problem.

"Learning in the context of original discovery, finding out something that no one has ever know before, really motivated me," said former UC Berkeley integrative biology undergraduate Talia Moore, now a graduate student in the Department of Organismic and Evolutionary Biology at Harvard University. "This research-based lab course … showed me how biologists and engineers can work together to benefit both fields."

"This paper shows that research-based teaching leads to better learning and simultaneously can lead to cutting-edge research," added Full, who last year briefed the U.S. House of Representative's Science, Technology, Engineering and Mathematics (STEM) Education Caucus on this topic. "It also shows the competitive advantage of interdisciplinary approaches and how involvement of undergraduates in research can lead to innovation."

From gecko toe hairs to tails

Full's research over the past 20 years has revealed how the toe hairs of geckos assist them in climbing smooth vertical surfaces and, more recently, how their tails help to keep them from falling when they slip and to right themselves in mid-air.

The new research tested a 40-year-old hypothesis that the two-legged theropod dinosaurs ‑ the ancestors of birds ‑ used their tails as stabilizers while running or dodging obstacles or predators. In Full's teaching laboratory, students noticed a lizard's recovery after slipping during a leap and thought a study of stumbling would be a perfect way to test the value of a tail.

In the CiBER lab, Full and six of his students used high-speed videography and motion capture to record how a red-headed African Agama lizard handled leaps from a platform with different degrees of traction, from slippery to easily-gripped.

They coaxed the lizards to run down a track, vault off a low platform and land on a vertical surface with a shelter on top. When the friction on the platform was reduced, lizards slipped, causing their bodies to potentially spin out of control.

When the researchers saw how the lizard used its tail to counteract the spin, they created a mathematical model as well as Tailbot -- a toy car equipped with a tail and small gyroscope to sense body position ‑ to better understand the animal's skills. With a tail but no feedback from sensors about body position, Tailbot took a nose dive when driven off a ramp, mimicking a lizard's take-off. When body position was sensed and fed back to the tail motor, however, Tailbot was able to stabilize its body in midair. The actively controlled tail effectively redirected the angular momentum of the body into the tail's swing, as happens with leaping lizards, Full said.

Inertial assisted robotics

Tailbot's design pushed the boundaries of control in robotics in an area researchers call inertial assisted robotics, an attention-grabber at last October's meeting of the International Conference on Intelligent Robots and Systems. The UC Berkeley researchers' paper, presented by Libby and fellow mechanical engineering graduate student Evan Chang-Siu, was one of five finalists there among more than 2,000 robot studies.

"Engineers quickly understood the value of a tail," Libby said, noting that when he dropped Tailbot nose-down, it was able to right itself before it had dropped a foot. "Robots are not nearly as agile as animals, so anything that can make a robot more stable is an advancement, which is why this work is so exciting."

Full and his students are now investigating the role of the tail in controlling pitch, roll and yaw while running.

UC Berkeley coauthors include Full and students Moore, Libby and Chang-Siu, along with Department of Integrative Biology undergraduate Deborah Li and graduate students Ardian Jusufi in the Department of Integrative Biology and Daniel Cohen in the Department of Bioengineering.

The work was funded by the National Science Foundation, including the NSF's Integrative Graduate Education and Research Traineeship (IGERT) program, and the Micro Autonomous Systems Technologies (MAST) consortium, a large group of researchers funded in part by the U.S. Army Research Laboratory that is focused on creating autonomous sensing robots.

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Engineers Create A Strong But Lightweight Isotruss Bike Using Carbon Fibers

Engineers Create A Strong But Lightweight Isotruss Bike Using Carbon Fibers

  3:14:00 AM    Science Lover

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Engineers used elements of architecture and geometry to create a strong but lightweight triangle-based isotruss bicycle frame. To make a road bike or mountain bike, the isotruss is first wound with carbon fiber using a sheet that holds the tension constant. The engineers then hand-wind Kevlar strands over the isotruss. The process creates a bike with a large strength-to-weight ratio.

Almost every kid has at one time or another asked for one for Christmas. Now, engineers have developed what may be the most technologically advanced bike to hit the road yet. It took ten years to develop a new incredibly light and strong model that will take cyclists into the future.

Karl Vizmeg has ridden his Delta 7 Arantix bike 1,700 miles. He has raced dozens of bikes, but says a new see-through model is the strongest and lightest.

"This is phenomenal," said Vizmeg. "I've had so much fun this year, particularly with the 'wow' factor, but [also] because it's such a great racing bike."

Vizmeg's $8,500 bike was handmade in Utah using geometry and architecture. To make bikes like his, workers first make an isotruss, a form made from isosceles triangles. Then, they wind carbon fiber around the form -- creating a great strength-to-weight ratio.

"We go back afterwards and hand-wind all the little Kevlar strands, inch-by-inch, over each isotruss," said Tyler Evans, program manager at Delta 7 Sports in Payson, Utah.

They then bake the bike to bond the materials. The mountain bike frame weighs 2.6 pounds. The new Ascend road bike weighs 1.8.

"This bike rides like bikes that are much heavier and stronger and built like a tank, but it's still in the featherweight category," Evans said.

You might think the open-lattice design wouldn't be aerodynamic, but Delta 7 says wind-tunnel tests prove the bikes are as aerodynamic as traditional ones. The Ascend bike has another advantage.

"You definitely feel like a rock star, like you're famous, like you belong in the Tour de France or some high-end race," cyclist Dan Weller told Ivanhoe.

Right now, that feeling requires patience. It takes about 100 hours to build each IsoTruss bike. Delta 7 produced only 200 IsoTruss models in 2008, but is working on ways to mass-produce them in the near future. To get one right now, you have to add yourself to the waiting list and put down a $1,000 deposit.

A SEE-THROUGH BIKE FRAME? The Arantix mountain bicycle and Ascend road bicycle have frames made from carbon fiber, shaped into a form called IsoTruss. The lattice structure is woven by hand into the form of pyramid-like shapes made of isosceles triangles (the kind with two sides of equal length). The design is specially designed to make the bicycle resistant to bending and twisting, with a greater ratio of strength to weight than metal frames. This technology is currently promoted as an alternative to heavier, weaker materials in everything from automobiles to building materials and utility poles.

HOW TO WEAVE A BICYCLE: To construct the bike, the artisans take a single strand of carbon fiber and wind it back and forth (by hand) over a cylindrical mandrill until it is the right size, then wrap Kevlar around the fibers to bundle it. Then they bake it in an oven, which bonds all the carbon together.

The Materials Research Society, the American Mathematical Society and the Mathematical Association of America contributed to the information contained in the TV portion of this report. This report has also been produced thanks to a generous grant from the Camille and Henry Dreyfus Foundation, Inc.

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Seeing in Stereo: Engineers Invent Lens for 3-D Microscope

Seeing in Stereo: Engineers Invent Lens for 3-D Microscope

  1:44:00 AM    Science Lover

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Engineers at Ohio State University have invented a lens that enables microscopic objects to be seen from nine different angles at once to create a 3-D image.

A lens invented at Ohio State University 
enables microscopes to capture 3-D images 
of tiny objects. (Credit: Photo by Kevin 
Fitzsimons, courtesy of Ohio State University.)

Other 3-D microscopes use multiple lenses or cameras that move around an object; the new lens is the first single, stationary lens to create microscopic 3-D images by itself.

Allen Yi, associate professor of integrated systems engineering at Ohio State, and postdoctoral researcher Lei Li described the lens in a recent issue of the Journal of the Optical Society of America A.

Yi called the lens a proof of concept for manufacturers of microelectronics and medical devices, who currently use very complex machinery to view the tiny components that they assemble.

Though the engineers milled their prototype thermoplastic lens on a precision cutting machine, the same lens could be manufactured less expensively through traditional molding techniques, Yi said.

"Ultimately, we hope to help manufacturers reduce the number and sizes of equipment they need to miniaturize products," he added.

The prototype lens, which is about the size of a fingernail, looks at first glance like a gem cut for a ring, with a flat top surrounded by eight facets. But while gemstones are cut for symmetry, this lens is not symmetric. The sizes and angles of the facets vary in minute ways that are hard to see with the naked eye.

"No matter which direction you look at this lens, you see a different shape," Yi explained. Such a lens is called a "freeform lens," a type of freeform optics.

Freeform optics have been in use for more than a decade. But Lei Li was able to write a computer program to design a freeform lens capable of imaging microscopic objects.

Then Yi and Li used a commercially available milling tool with a diamond blade to cut the shape from a piece of the common thermoplastic material polymethyl methacrylate, a transparent plastic that is sometimes called acrylic glass. The machine shaved bits of plastic from the lens in increments of 10 nanometers, or 10 billionths of a meter -- a distance about 5,000 times smaller than the diameter of a human hair.

The final lens resembled a rhinestone, with a faceted top and a wide, flat bottom. They installed the lens on a microscope with a camera looking down through the faceted side, and centered tiny objects beneath the flat side.

Each facet captured an image of the objects from a different angle, which can be combined on a computer into a 3-D image.

The engineers successfully recorded 3-D images of the tip of a ballpoint pen -- which has a diameter of about 1 millimeter -- and a mini drill bit with a diameter of 0.2 millimeters.

"Using our lens is basically like putting several microscopes into one microscope," said Li. "For us, the most attractive part of this project is we will be able to see the real shape of micro-samples instead of just a two-dimensional projection."

In the future, Yi would like to develop the technology for manufacturers. He pointed to the medical testing industry, which is working to shrink devices that analyze fluid samples. Cutting tiny reservoirs and channels in plastic requires a clear view, and the depths must be carved with precision.

Computer-controlled machines -- rather than humans -- do the carving, and Yi says that the new lens can be placed in front of equipment that is already in use. It can also simplify the design of future machine vision equipment, since multiple lenses or moving cameras would no longer be necessary.

Other devices could use the tiny lens, and he and Li have since produced a grid-shaped array of lenses made to fit an optical sensor. Another dome-shaped lens is actually made of more than 1,000 tiny lenses, similar in appearance to an insect's eye.

This research was sponsored by the National Science Foundation. Moore Nanotechnology Systems in Keene, NH, provided the ultraprecision milling machine.

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Engineers Make Artificial Skin out of Nanowires

Engineers Make Artificial Skin out of Nanowires

  1:13:00 AM    Science Lover

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Engineers at the University of California, Berkeley, have developed a pressure-sensitive electronic material from semiconductor nanowires that could one day give new meaning to the term "thin-skinned."

This is an artist's illustration of an artificial e-skin 
 with nanowire active matrix circuitry covering a hand.
A fragile egg is held, illustrating the functionality of 
the e-skin device for prosthetic and robotic applications. 
(Credit: Ali Javey and Kuniharu Takei)

"The idea is to have a material that functions like the human skin, which means incorporating the ability to feel and touch objects," said Ali Javey, associate professor of electrical engineering and computer sciences and head of the UC Berkeley research team developing the artificial skin.

The artificial skin, dubbed "e-skin" by the UC Berkeley researchers, is described in a Sept. 12 paper in the advanced online publication of the journal Nature Materials. It is the first such material made out of inorganic single crystalline semiconductors.

A touch-sensitive artificial skin would help overcome a key challenge in robotics: adapting the amount of force needed to hold and manipulate a wide range of objects.

"Humans generally know how to hold a fragile egg without breaking it," said Javey, who is also a member of the Berkeley Sensor and Actuator Center and a faculty scientist at the Lawrence Berkeley National Laboratory Materials Sciences Division. "If we ever wanted a robot that could unload the dishes, for instance, we'd want to make sure it doesn't break the wine glasses in the process. But we'd also want the robot to be able to grip a stock pot without dropping it."

A longer term goal would be to use the e-skin to restore the sense of touch to patients with prosthetic limbs, which would require significant advances in the integration of electronic sensors with the human nervous system.

Previous attempts to develop an artificial skin relied upon organic materials because they are flexible and easier to process.

"The problem is that organic materials are poor semiconductors, which means electronic devices made out of them would often require high voltages to operate the circuitry," said Javey. "Inorganic materials, such as crystalline silicon, on the other hand, have excellent electrical properties and can operate on low power. They are also more chemically stable. But historically, they have been inflexible and easy to crack. In this regard, works by various groups, including ours, have recently shown that miniaturized strips or wires of inorganics can be made highly flexible -- ideal for high performance, mechanically bendable electronics and sensors."

The UC Berkeley engineers utilized an innovative fabrication technique that works somewhat like a lint roller in reverse. Instead of picking up fibers, nanowire "hairs" are deposited.

The researchers started by growing the germanium/silicon nanowires on a cylindrical drum, which was then rolled onto a sticky substrate. The substrate used was a polyimide film, but the researchers said the technique can work with a variety of materials, including other plastics, paper or glass. As the drum rolled, the nanowires were deposited, or "printed," onto the substrate in an orderly fashion, forming the basis from which thin, flexible sheets of electronic materials could be built.

In another complementary approach utilized by the researchers, the nanowires were first grown on a flat source substrate, and then transferred to the polyimide film by a direction-rubbing process.

For the e-skin, the engineers printed the nanowires onto an 18-by-19 pixel square matrix measuring 7 centimeters on each side. Each pixel contained a transistor made up of hundreds of semiconductor nanowires. Nanowire transistors were then integrated with a pressure sensitive rubber on top to provide the sensing functionality. The matrix required less than 5 volts of power to operate and maintained its robustness after being subjected to more than 2,000 bending cycles.

The researchers demonstrated the ability of the e-skin to detect pressure from 0 to 15 kilopascals, a range comparable to the force used for such daily activities as typing on a keyboard or holding an object. In a nod to their home institution, the researchers successfully mapped out the letter C in Cal.

"This is the first truly macroscale integration of ordered nanowire materials for a functional system -- in this case, an electronic skin," said study lead author Kuniharu Takei, post-doctoral fellow in electrical engineering and computer sciences. "It's a technique that can be potentially scaled up. The limit now to the size of the e-skin we developed is the size of the processing tools we are using."

Other UC Berkeley co-authors of the paper are Ron Fearing, professor of electrical engineering and computer sciences; Toshitake Takahashi, graduate student in electrical engineering and computer sciences; Johnny C. Ho, graduate student in materials science and engineering; Hyunhyub Ko and Paul Leu, post-doctoral researchers in electrical engineering and computer sciences; and Andrew G. Gillies, graduate student in mechanical engineering.

The National Science Foundation and the Defense Advanced Research Projects Agency helped support this research.

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Radio Waves 'See' Through Walls

Radio Waves 'See' Through Walls

  1:26:00 PM    Science Lover

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University of Utah engineers showed that a wireless network of radio transmitters can track people moving behind solid walls. The system could help police, firefighters and others nab intruders, and rescue hostages, fire victims and elderly people who fall in their homes. It also might help retail marketing and border control.

On the left, a person walks around inside a square of 28 radio transceivers (mounted on plastic pipes) in the Warnock Engineering Building's atrium at the University of Utah. The person creates "shadows" in the radio waves, resulting in the image displayed on right, in which the person appears as a reddish-orange-yellow blob. University of Utah engineers also showed this method can "see" through walls to make blurry images of people moving behind the walls. They hope the technique will help police, firefighters and other emergency responders apprehend burglars and rescue hostages, fire victims and others. (Credit: Sarang Joshi and Joey Wilson, University of Utah)

"By showing the locations of people within a building during hostage situations, fires or other emergencies, radio tomography can help law enforcement and emergency responders to know where they should focus their attention," Joey Wilson and Neal Patwari wrote in one of two new studies of the method.

Both researchers are in the university's Department of Electrical and Computer Engineering – Patwari as an assistant professor and Wilson as a doctoral student.

Their method uses radio tomographic imaging (RTI), which can "see," locate and track moving people or objects in an area surrounded by inexpensive radio transceivers that send and receive signals. People don't need to wear radio-transmitting ID tags.

One of the studies – which outlines the method and tests it in an indoor atrium and a grassy area with trees – is awaiting publication soon in IEEE Transactions on Mobile Computing, a journal of the Institute of Electrical and Electronics Engineers.

The study involved placing a wireless network of 28 inexpensive radio transceivers – called nodes – around a square-shaped portion of the atrium and a similar part of the lawn. In the atrium, each side of the square was almost 14 feet long and had eight nodes spaced 2 feet apart. On the lawn, the square was about 21 feet on each side and nodes were 3 feet apart. The transceivers were placed on 4-foot-tall stands made of plastic pipe so they would make measurements at human torso level.

Radio signal strengths between all nodes were measured as a person walked in each area. Processed radio signal strength data were displayed on a computer screen, producing a bird's-eye-view, blob-like image of the person.

A second study detailed a test of an improved method that allows "tracking through walls." That study has been placed on arXiv.org, an online archive for preprints of scientific papers. The study details how variations in radio signal strength within a wireless network of 34 nodes allowed tracking of moving people behind a brick wall.

The method was tested around an addition to Patwari's Salt Lake City home. Variations in radio waves were measured as Wilson walked around inside. The system successfully tracked Wilson's location to within 3 feet.

The wireless system used in the experiments was not a Wi-Fi network like those that link home computers, printers and other devices. Patwari says the system is known as a Zigbee network – the kind of network often used by wireless home thermostats and other home or factory automation.

Wilson demonstrated radio tomographic imaging during a mobile communication conference last year, and won the MobiCom 2008 Student Research Demo Competition. The researchers now have a patent pending on the method.

"I have aspirations to commercialize this," says Wilson, who has founded a spinoff company named Xandem Technology LLC in Salt Lake City.

The research was funded by the National Science Foundation.

How It Works

Radio tomographic imaging (RTI) is different and much less expensive than radar, in which radar or radio signals are bounced off targets and the returning echoes or reflections provide the target's location and speed. RTI instead measures "shadows" in radio waves created when they pass through a moving person or object.

RTI measures radio signal strengths on numerous paths as the radio waves pass through a person or other target. In that sense, it is quite similar to medical CT (computerized tomographic) scanning, which uses X-rays to make pictures of the human body, and seismic imaging, in which waves from earthquakes or explosions are used to look for oil, minerals and rock structures underground. In each method, measurements of the radio waves, X-rays or seismic waves are made along many different paths through the target, and those measurements are used to construct a computer image.

In their indoor, outdoor and through-the-wall experiments, Wilson and Patwari obtained radio signal strength measurements from all the transceivers – first when the rectangle was empty and then when a person walked through it. They developed math formulas and used them in a computer program to convert weaker or "attenuated" signals – which occur when someone creates "shadows" by walking through the radio signals – into a blob-like, bird's-eye-view image of that person walking.

RTI has advantages. "RF [radio frequency] signals can travel through obstructions such as walls, trees and smoke, while optical and infrared imaging systems cannot," the engineers wrote. "RF imaging will also work in the dark, where video cameras will fail."

Even "where video cameras could work, privacy concerns may prevent their deployment," Wilson and Patwari wrote. "An RTI system provides current images of the location of people and their movements, but cannot be used to identify a person."

Would bombardment by radio waves pose a hazard? Wilson says the devices "transmit radio waves at powers 500 times less than a typical cell phone."

"And you don't hold it against your head," Patwari adds.

Radio 'Eyes' to the Rescue

Patwari says the system still needs improvements, "but the plan is that when there is a hostage situation, for example, or some kind of event that makes it dangerous for police or firefighters to enter a building, then instead of entering the building first, they would throw dozens of these radios around the building and immediately they would be able to see a computer image showing where people are moving inside the building."

"They are reusable and you can pick them up afterwards," he says.

The technique cannot distinguish good guys from bad guys, but at least will tell emergency personnel where people are located, he adds.

Patwari says radio tomography probably can be improved to detect people in a burning building, but also would "see" moving flames. "You may be able to look at the image and say this is a spreading fire and these are people," says Patwari.

Wilson believes radio imaging also could be used in "a smarter alarm system. … What if you put radios in your home [built into walls or plugged into outlets] and used tomography to locate people in your home. Not only would your security system be triggered by an intrusion, but you could track the intruder online or over your phone."

Radio tomography even might be used to study where people spend time in stores.

"Does a certain marketing display get people to stop or does it not?" Wilson asks. "I'm thinking of retail stores or grocery stores. They spend a lot of money to determine, 'Where should we put the cereal, where should we put the milk, where should we put the bread?' If I can offer that information using radio tomographic imaging, it's a big deal."

Radio image tracking might help some elderly people live at home. "The elderly want to stay in their homes but don't want a camera in their face all day," Wilson says. "With radio tomographic imaging, you could track where they are in their home, did they get up at the right time, did they go to the medicine cabinet, have they not moved today?"

Wilson says a computer monitoring the radio images might detect an elderly person falling down the stairs based on the unusually fast movement.

He says radio tracking also might be a relatively inexpensive method of border security, and would work in dark and fog unlike cameras.

Another possible use: automatic control of lighting, heating and air conditioning in buildings, says Wilson. Radio tracking might even control sound systems so that the best sound is aimed where people are located, as well as noise cancellation systems which could be aimed automatically at noise sources, Patwari says.
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Artificial Foot Recycles Energy for Easier Walking

Artificial Foot Recycles Energy for Easier Walking

  1:01:00 AM    Science Lover

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An artificial foot that recycles energy otherwise wasted in between steps could make it easier for amputees to walk, its developers say.

Developers say that an artificial foot that recycles energy otherwise wasted in between steps could make it easier for amputees to walk. (Credit: Image courtesy of University of Michigan)

"For amputees, what they experience when they're trying to walk normally is what I would experience if I were carrying an extra 30 pounds," said Art Kuo, professor in the University of Michigan departments of Biomedical Engineering and Mechanical Engineering.

Compared with conventional prosthetic feet, the new prototype device significantly cuts the energy spent per step.

A paper about the device is published in the Feb. 17 edition of in the journal PLoS ONE. The foot was created by Kuo and Steve Collins, who was then a U-M graduate student. Now Collins is an associate research fellow at Delft University of Technology in the Netherlands.

The human walking gait naturally wastes energy as each foot collides with the ground in between steps.

A typical prosthesis doesn't reproduce the force a living ankle exerts to push off of the ground. As a result, test subjects spent 23 percent more energy walking with a conventional prosthetic foot, compared with walking naturally. To test how stepping with their device compared with normal walking, the engineers conducted their experiments with non-amputees wearing a rigid boot and prosthetic simulator.

In their energy-recycling foot, the engineers put the wasted walking energy to work enhancing the power of ankle push-off. The foot naturally captures the dissipated energy. A microcontroller tells the foot to return the energy to the system at precisely the right time.

Based on metabolic rate measurements, the test subjects spent 14 percent more energy walking in energy-recycling artificial foot than they did walking naturally. That's a significant decrease from the 23 percent more energy they used in the conventional prosthetic foot, Kuo says.

"We know there's an energy penalty in using an artificial foot," Kuo said. "We're almost cutting that penalty in half."

He explained how this invention differs from current technologies.

"All prosthetic feet store and return energy, but they don't give you a choice about when and how. They just return it whenever they want," Kuo said. "This is the first device to release the energy in the right way to supplement push-off, and to do so without an external power source."

Other devices that boost push-off power use motors and require large batteries.

Because the energy-recycling foot takes advantage of power that would otherwise be lost, it uses less than 1 Watt of electricity through a small, portable battery.

"Individuals with lower limb amputations, such as veterans of the conflicts in Iraq and Afghanistan or patients suffering from diabetes, often find walking a difficult task. Our new design may restore function and reduce effort for these users," Collins said. "With further progress, robotic limbs may yet beat their biological forerunners."

This paper demonstrates that the engineers' idea works. They are now testing the foot on amputees at the Seattle Veterans Affairs Medical Center. Commercial devices based on the technology are under development by an Ann Arbor company. This research was funded by the National Institutes of Health and the Department of Veterans Affairs.

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Researchers Create Nanopatch for the Heart

Researchers Create Nanopatch for the Heart

  12:45:00 AM    Science Lover

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Engineers at Brown University and in India have a promising new approach to treating heart-attack victims. The researchers created a nanopatch with carbon nanofibers and a polymer. In laboratory tests, natural heart-tissue cell density on the nanoscaffold was six times greater than the control sample, while neuron density had doubled.

Beating heart. Engineers at Brown University have 
created a nanopatch for the heart that tests show 
restores areas that have been damaged, such as 
from a heart attack. Credit: Frank Mullin/Brown 
University (Credit: Image courtesy of Brown University)

When you suffer a heart attack, a part of your heart dies. Nerve cells in the heart's wall and a special class of cells that spontaneously expand and contract -- keeping the heart beating in perfect synchronicity -- are lost forever. Surgeons can't repair the affected area. It's as if when confronted with a road riddled with potholes, you abandon what's there and build a new road instead.

Needless to say, this is a grossly inefficient way to treat arguably the single most important organ in the human body. The best approach would be to figure out how to resuscitate the deadened area, and in this quest, a group of researchers at Brown University and in India may have an answer.

The scientists turned to nanotechnology. In a lab, they built a scaffold-looking structure consisting of carbon nanofibers and a government-approved polymer. Tests showed the synthetic nanopatch regenerated natural heart tissue cells ­- called cardiomyocytes -- as well as neurons. In short, the tests showed that a dead region of the heart can be brought back to life.

"This whole idea is to put something where dead tissue is to help regenerate it, so that you eventually have a healthy heart," said David Stout, a graduate student in the School of Engineering at Brown and the lead author of the paper published in Acta Biomaterialia.

The approach, if successful, would help millions of people. In 2009, some 785,000 Americans suffered a new heart attack linked to weakness caused by the scarred cardiac muscle from a previous heart attack, according to the American Heart Association. Just as ominously, a third of women and a fifth of men who have experienced a heart attack will have another one within six years, the researchers added, citing the American Heart Association.

What is unique about the experiments at Brown and at the India Institute of Technology Kanpur is the engineers employed carbon nanofibers, helical-shaped tubes with diameters between 60 and 200 nanometers. The carbon nanofibers work well because they are excellent conductors of electrons, performing the kind of electrical connections the heart relies upon for keeping a steady beat. The researchers stitched the nanofibers together using a poly lactic-co-glycolic acid polymer to form a mesh about 22 millimeters long and 15 microns thick and resembling "a black Band Aid," Stout said. They laid the mesh on a glass substrate to test whether cardiomyocytes would colonize the surface and grow more cells.

In tests with the 200-nanometer-diameter carbon nanofibers seeded with cardiomyocytes, five times as many heart-tissue cells colonized the surface after four hours than with a control sample consisting of the polymer only. After five days, the density of the surface was six times greater than the control sample, the researchers reported. Neuron density had also doubled after four days, they added.

The scaffold works because it is elastic and durable, and can thus expand and contract much like heart tissue, said Thomas Webster, associate professor in engineering and orthopaedics at Brown and the corresponding author on the paper. It's because of these properties and the carbon nanofibers that cardiomyocytes and neurons congregate on the scaffold and spawn new cells, in effect regenerating the area.

The scientists want to tweak the scaffold pattern to better mimic the electrical current of the heart, as well as build an in-vitro model to test how the material reacts to the heart's voltage and beat regime. They also want to make sure the cardiomyocytes that grow on the scaffolds are endowed with the same abilities as other heart-tissue cells.

Bikramjit Basu at the India Institute of Technology Kanpur contributed to the paper. The Indo-U.S. Science and Technology Forum, the Hermann Foundation, the Indian Institute of Technology, Kanpur, the government of India and California State University funded the research.

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Engineers Solve Longstanding Problem in Photonic Chip Technology: Findings Help Pave Way for Next Generation of Computer Chips

Engineers Solve Longstanding Problem in Photonic Chip Technology: Findings Help Pave Way for Next Generation of Computer Chips

  1:00:00 AM    Science Lover

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Stretching for thousands of miles beneath oceans, optical fibers now connect every continent except for Antarctica. With less data loss and higher bandwidth, optical-fiber technology allows information to zip around the world, bringing pictures, video, and other data from every corner of the globe to your computer in a split second. But although optical fibers are increasingly replacing copper wires, carrying information via photons instead of electrons, today's computer technology still relies on electronic chips.

Caltech engineers have developed a new way to 
isolate light on a photonic chip, allowing light to 
travel in only one direction. This finding can lead 
to the next generation of computer-chip technology: 
photonic chips that allow for faster computers 
and less data loss. (Credit: Caltech/Liang Feng)

Now, researchers led by engineers at the California Institute of Technology (Caltech) are paving the way for the next generation of computer-chip technology: photonic chips. With integrated circuits that use light instead of electricity, photonic chips will allow for faster computers and less data loss when connected to the global fiber-optic network.

"We want to take everything on an electronic chip and reproduce it on a photonic chip," says Liang Feng, a postdoctoral scholar in electrical engineering and the lead author on a paper to be published in the August 5 issue of the journal Science. Feng is part of Caltech's nanofabrication group, led by Axel Scherer, Bernard A. Neches Professor of Electrical Engineering, Applied Physics, and Physics, and co-director of the Kavli Nanoscience Institute at Caltech.

In that paper, the researchers describe a new technique to isolate light signals on a silicon chip, solving a longstanding problem in engineering photonic chips.

An isolated light signal can only travel in one direction. If light weren't isolated, signals sent and received between different components on a photonic circuit could interfere with one another, causing the chip to become unstable. In an electrical circuit, a device called a diode isolates electrical signals by allowing current to travel in one direction but not the other. The goal, then, is to create the photonic analog of a diode, a device called an optical isolator. "This is something scientists have been pursuing for 20 years," Feng says.

Normally, a light beam has exactly the same properties when it moves forward as when it's reflected backward. "If you can see me, then I can see you," he says. In order to isolate light, its properties need to somehow change when going in the opposite direction. An optical isolator can then block light that has these changed properties, which allows light signals to travel only in one direction between devices on a chip.

"We want to build something where you can see me, but I can't see you," Feng explains. "That means there's no signal from your side to me. The device on my side is isolated; it won't be affected by my surroundings, so the functionality of my device will be stable."

To isolate light, Feng and his colleagues designed a new type of optical waveguide, a 0.8-micron-wide silicon device that channels light. The waveguide allows light to go in one direction but changes the mode of the light when it travels in the opposite direction.

A light wave's mode corresponds to the pattern of the electromagnetic field lines that make up the wave. In the researchers' new waveguide, the light travels in a symmetric mode in one direction, but changes to an asymmetric mode in the other. Because different light modes can't interact with one another, the two beams of light thus pass through each other.



Previously, there were two main ways to achieve this kind of optical isolation. The first way -- developed almost a century ago -- is to use a magnetic field. The magnetic field changes the polarization of light -- the orientation of the light's electric-field lines -- when it travels in the opposite direction, so that the light going one way can't interfere with the light going the other way. "The problem is, you can't put a large magnetic field next to a computer," Feng says. "It's not healthy."

The second conventional method requires so-called nonlinear optical materials, which change light's frequency rather than its polarization. This technique was developed about 50 years ago, but is problematic because silicon, the material that's the basis for the integrated circuit, is a linear material. If computers were to use optical isolators made out of nonlinear materials, silicon would have to be replaced, which would require revamping all of computer technology. But with their new silicon waveguides, the researchers have become the first to isolate light with a linear material.

Although this work is just a proof-of-principle experiment, the researchers are already building an optical isolator that can be integrated onto a silicon chip. An optical isolator is essential for building the integrated, nanoscale photonic devices and components that will enable future integrated information systems on a chip. Current, state-of-the-art photonic chips operate at 10 gigabits per second (Gbps) -- hundreds of times the data-transfer rates of today's personal computers -- with the next generation expected to soon hit 40 Gbps. But without built-in optical isolators, those chips are much simpler than their electronic counterparts and are not yet ready for the market. Optical isolators like those based on the researchers' designs will therefore be crucial for commercially viable photonic chips.

In addition to Feng and Scherer, the other authors on the Science paper, "Non-reciprocal light propagation in a silicon photonic circuit," are Jingqing Huang, a Caltech graduate student; Maurice Ayache of UC San Diego and Yeshaiahu Fainman, Cymer Professor in Advanced Optical Technologies at UC San Diego; and Ye-Long Xu, Ming-Hui Lu, and Yan-Feng Chen of the Nanjing National Laboratory of Microstructures in China. This research was done as part of the Center for Integrated Access Networks (CIAN), one of the National Science Foundation's Engineering Research Centers. Fainman is also the deputy director of CIAN. Funding was provided by the National Science Foundation, and the Defense Advanced Research Projects Agency.

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Solar Cells Thinner Than Wavelengths of Light Hold Huge Power Potential

Solar Cells Thinner Than Wavelengths of Light Hold Huge Power Potential

  10:21:00 AM    Science Lover

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Ultra-thin solar cells can absorb sunlight more efficiently than the thicker, more expensive-to-make silicon cells used today, because light behaves differently at scales around a nanometer (a billionth of a meter), say Stanford engineers. They calculate that by properly configuring the thicknesses of several thin layers of films, an organic polymer thin film could absorb as much as 10 times more energy from sunlight than was thought possible.

This schematic diagram of a thin film organic solar 
cell shows the top layer, a patterned, roughened
scattering layer, in green. The organic thin film layer, 
shown in red, is where light is trapped and electrical
current is generated. The film is sandwiched between 
two layers that help keep light contained within 
the thin film. (Credit: Reproduced with permission
from Proceedings of the National Academy 
of Sciences USA)

In the smooth, white, bunny-suited clean-room world of silicon wafers and solar cells, it turns out that a little roughness may go a long way, perhaps all the way to making solar power an affordable energy source, say Stanford engineers.

Their research shows that light ricocheting around inside the polymer film of a solar cell behaves differently when the film is ultra thin. A film that's nanoscale-thin and has been roughed up a bit can absorb more than 10 times the energy predicted by conventional theory.

The key to overcoming the theoretical limit lies in keeping sunlight in the grip of the solar cell long enough to squeeze the maximum amount of energy from it, using a technique called "light trapping." It's the same as if you were using hamsters running on little wheels to generate your electricity -- you'd want each hamster to log as many miles as possible before it jumped off and ran away.

"The longer a photon of light is in the solar cell, the better chance the photon can get absorbed," said Shanhui Fan, associate professor of electrical engineering. The efficiency with which a given material absorbs sunlight is critically important in determining the overall efficiency of solar energy conversion. Fan is senior author of a paper describing the work published online by Proceedings of the National Academy of Sciences.

Light trapping has been used for several decades with silicon solar cells and is done by roughening the surface of the silicon to cause incoming light to bounce around inside the cell for a while after it penetrates, rather than reflecting right back out as it does off a mirror. But over the years, no matter how much researchers tinkered with the technique, they couldn't boost the efficiency of typical "macroscale" silicon cells beyond a certain amount.

Eventually the scientists realized that there was a physical limit related to the speed at which light travels within a given material.

But light has a dual nature, sometimes behaving as a solid particle (a photon) and other times as a wave of energy, and Fan and postdoctoral researcher Zongfu Yu decided to explore whether the conventional limit on light trapping held true in a nanoscale setting. Yu is the lead author of the PNAS paper.

"We all used to think of light as going in a straight line," Fan said. "For example, a ray of light hits a mirror, it bounces and you see another light ray. That is the typical way we think about light in the macroscopic world.

"But if you go down to the nanoscales that we are interested in, hundreds of millionths of a millimeter in scale, it turns out the wave characteristic really becomes important."

Visible light has wavelengths around 400 to 700 nanometers (billionths of a meter), but even at that small scale, Fan said, many of the structures that Yu analyzed had a theoretical limit comparable to the conventional limit proven by experiment.

"One of the surprises with this work was discovering just how robust the conventional limit is," Fan said.

It was only when Yu began investigating the behavior of light inside a material of deep subwavelength-scale -- substantially smaller than the wavelength of the light -- that it became evident to him that light could be confined for a longer time, increasing energy absorption beyond the conventional limit at the macroscale.

"The amount of benefit of nanoscale confinement we have shown here really is surprising," said Yu. "Overcoming the conventional limit opens a new door to designing highly efficient solar cells."

Yu determined through numerical simulations that the most effective structure for capitalizing on the benefits of nanoscale confinement was a combination of several different types of layers around an organic thin film.

He sandwiched the organic thin film between two layers of material -- called "cladding" layers -- that acted as confining layers once the light passed through the upper one into the thin film. Atop the upper cladding layer, he placed a patterned rough-surfaced layer designed to send the incoming light off in different directions as it entered the thin film.

By varying the parameters of the different layers, he was able to achieve a 12-fold increase in the absorption of light within the thin film, compared to the macroscale limit.

Nanoscale solar cells offer savings in material costs, as the organic polymer thin films and other materials used are less expensive than silicon and, being nanoscale, the quantities required for the cells are much smaller.

The organic materials also have the advantage of being manufactured in chemical reactions in solution, rather than needing high-temperature or vacuum processing, as is required for silicon manufacture.

"Most of the research these days is looking into many different kinds of materials for solar cells," Fan said. "Where this will have a larger impact is in some of the emerging technologies; for example, in organic cells."

"If you do it right, there is enormous potential associated with it," Fan said.

Aaswath Raman, a graduate student in applied physics, also worked on the research and is a coauthor of the paper.

The project was supported by funding from the King Abdullah University of Science and Technology, which supports the Center for Advanced Molecular Photovoltaics at Stanford, and by the U.S. Department of Energy.

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