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Showing posts with label Fuel Cells. Show all posts
Showing posts with label Fuel Cells. Show all posts

Sunday, April 20, 2014

Sugar-powered biobattery has 10 times the energy storage of lithium: Your smartphone might soon run on enzymes


As you probably know, from sucking down cans of Coke and masticating on candy, sugar — glucose, fructose, sucrose, dextrose — is an excellent source of energy. Biologically speaking, sugar molecules are energy-dense, easy to transport, and cheap to digest. There is a reason why almost every living cell on Earth generates its energy (ATP) from glucose. Now, researchers at Virginia Tech have successfully created a sugar-powered fuel cell that has an energy storage density of 596 amp-hours per kilo — or “one order of magnitude” higher than lithium-ion batteries. This fuel cell is refillable with a solution of maltodextrin, and its only by products are electricity and water. The chief researcher, Y.H. Percival Zhang, says the tech could be commercialized in as soon as three years.


Now, it’s not exactly news that sugar is an excellent energy source. As a culture we’ve probably known about it since before we were Homo sapiens. The problem is, unless you’re a living organism or some kind of incendiary device, extracting that energy is difficult. In nature, an enzymatic pathway is used — a production line of tailor-made enzymes that meddle with the glucose molecules until they become ATP. Because it’s easy enough to produce enzymes in large quantities, researchers have tried to create fuel cells that use artificial “metabolism” to break down glucose into electricity (biobatteries), but it has historically proven very hard to find the right pathway for maximum efficiency and to keep the enzymes in the right place over a long period of time.


A diagram of the enzymatic fuel cell. The little Pac-Man things are enzymes.
Now, however, Zhang and friends at Virginia Tech appear to have built a high-density fuel cell that uses an enzymatic pathway to create a lot of electricity from glucose. There doesn’t seem to be much information on how stable this biobattery is over multiple refills, but if Zhang thinks it could be commercialized in three years, that’s a very good sign. Curiously, the research paper says that the enzymes are non-immobilized — meaning Zhang found a certain battery chemistry that doesn’t require the enzymes to be kept in place… or, alternatively, that it will only work for a very short time.

The Virginia Tech biobattery uses 13 enzymes, plus air (it’s an air-breathing biobattery), to produce nearly 24 electrons from a single glucose unit. This equates to a power output of 0.8 mW/cm, current density of 6 mA/cm, and energy storage density of 596 Ah/kg. This last figure is impressive, at roughly 10 times the energy density of the lithium-ion batteries in your mobile devices. [Research paper: doi:10.1038/ncomms4026 - "A high-energy-density sugar biobattery based on a synthetic enzymatic pathway"]

If Zhang’s biobatteries pan out, you might soon be recharging your smartphone by pouring in a solution of 15% maltodextrin. That battery would not only be very safe (it produces water and electricity), but very cheap to run and very green. This seems to fit in perfectly with Zhang’s homepage, which talks about how his main goals in life are replacing crude oil with sugar, and feeding the world.

The other area in which biobatteries might be useful is powering implanted devices, such as pacemakers — or, in the future, subcutaneous sensors and computers. Such a biobattery could feed on the glucose in your bloodstream, providing an endless supply of safe electricity for the myriad implants that futuristic technocrats will surely have.
 

Wednesday, April 4, 2012

Electricity and Carbon Dioxide Used to Generate Alternative Fuel



Imagine being able to use electricity to power your car -- even if it's not an electric vehicle. Researchers at the UCLA Henry Samueli School of Engineering and Applied Science have for the first time demonstrated a method for converting carbon dioxide into liquid fuel isobutanol using electricity.

Producing fuel from CO2 and sunlight.
Producing fuel from CO2 and sunlight. (Credit: Image
courtesy of University of California - Los Angeles)

Today, electrical energy generated by various methods is still difficult to store efficiently. Chemical batteries, hydraulic pumping and water splitting suffer from low energy-density storage or incompatibility with current transportation infrastructure.

In a study published March 30 in the journal Science, James Liao, UCLA's Ralph M. Parsons Foundation Chair in Chemical Engineering, and his team report a method for storing electrical energy as chemical energy in higher alcohols, which can be used as liquid transportation fuels.

"The current way to store electricity is with lithium ion batteries, in which the density is low, but when you store it in liquid fuel, the density could actually be very high," Liao said. "In addition, we have the potential to use electricity as transportation fuel without needing to change current infrastructure."

Liao and his team genetically engineered a lithoautotrophic microorganism known as Ralstonia eutropha H16 to produce isobutanol and 3-methyl-1-butanol in an electro-bioreactor using carbon dioxide as the sole carbon source and electricity as the sole energy input.

Photosynthesis is the process of converting light energy to chemical energy and storing it in the bonds of sugar. There are two parts to photosynthesis -- a light reaction and a dark reaction. The light reaction converts light energy to chemical energy and must take place in the light. The dark reaction, which converts CO2 to sugar, doesn't directly need light to occur.

"We've been able to separate the light reaction from the dark reaction and instead of using biological photosynthesis, we are using solar panels to convert the sunlight to electrical energy, then to a chemical intermediate, and using that to power carbon dioxide fixation to produce the fuel," Liao said. "This method could be more efficient than the biological system."

Liao explained that with biological systems, the plants used require large areas of agricultural land. However, because Liao's method does not require the light and dark reactions to take place together, solar panels, for example, can be built in the desert or on rooftops.

Theoretically, the hydrogen generated by solar electricity can drive CO2 conversion in lithoautotrophic microorganisms engineered to synthesize high-energy density liquid fuels. But the low solubility, low mass-transfer rate and the safety issues surrounding hydrogen limit the efficiency and scalability of such processes. Instead Liao's team found formic acid to be a favorable substitute and efficient energy carrier.

"Instead of using hydrogen, we use formic acid as the intermediary," Liao said. "We use electricity to generate formic acid and then use the formic acid to power the CO2 fixation in bacteria in the dark to produce isobutanol and higher alcohols."

The electrochemical formate production and the biological CO2 fixation and higher alcohol synthesis now open up the possibility of electricity-driven bioconversion of CO2 to a variety of chemicals. In addition, the transformation of formate into liquid fuel will also play an important role in the biomass refinery process, according to Liao.

"We've demonstrated the principle, and now we think we can scale up," he said. "That's our next step."

The study was funded by a grant from the U.S. Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E).